Methyl Radical in Irradiated Single Crystals of Sodium Acetate Trihydrate

作者: Max T. Rogers , L. D. Kispert

DOI: 10.1063/1.1840376

关键词:

摘要: The ESR spectra of irradiated single crystals sodium acetate trihydrate and three isotopically substituted species have been examined at 77°K. hyperfine proton 13C splittings provide strong evidence for the presence trapped methyl radicals anisotropic splitting tensors evaluated are discussed. planar radical is reorienting rapidly about its threefold axis.

参考文章(6)
J. Turkevich, Y. Fujita, Methyl radicals: preparation and stabilization. Science. ,vol. 152, pp. 1619- 1621 ,(1966) , 10.1126/SCIENCE.152.3729.1619
G. T. Trammell, Henry Zeldes, Ralph Livingston, EFFECT OF ENVIRONMENTAL NUCLEI IN ELECTRON SPIN RESONANCE SPECTROSCOPY Physical Review. ,vol. 110, pp. 630- 634 ,(1958) , 10.1103/PHYSREV.110.630
H. Shimizu, Spin Relaxation and Differential Saturation of ESR Multiple Lines Journal of Chemical Physics. ,vol. 42, pp. 3603- 3612 ,(1965) , 10.1063/1.1695766
D. M. Schrader, M. Karplus, Orbital Following in the Methyl Radical The Journal of Chemical Physics. ,vol. 40, pp. 1593- 1601 ,(1964) , 10.1063/1.1725366
J. R. Morton, ELECTRON SPIN RESONANCE SPECTRA OF ORIENTED RADICALS Chemical Reviews. ,vol. 64, pp. 453- 471 ,(1964) , 10.1021/CR60230A005
Ichiro Miyagawa, Walter Gordy, Deuterium Substitution in an Electron Spin Resonance Study of Radiation-induced Free Radicals1a Journal of the American Chemical Society. ,vol. 83, pp. 1036- 1040 ,(1961) , 10.1021/JA01466A006