Selective pore filling of mesoporous CMK-5 carbon studied by XRD: Comparison between theoretical simulations and experimental results
作者： Christian Weinberger , Marc Hartmann , Sai Ren , Thomas Sandberg , Jan-Henrik Smått
DOI: 10.1016/J.MICROMESO.2018.02.035
关键词:
摘要: Abstract It is possible to infiltrate a guest species selectively in one pore system of bimodal mesoporous CMK-5 carbon by an optimized nanocasting procedure. The selective filling has drastic impact on the low-angle X-ray diffraction pattern this novel class materials. structures CMK-5, composite materials (sulfur and SnO2 as species), CMK-3 were simulated investigate influence with different compared experimental results. Additionally, structural defects taken into account. nature strongly influences relative intensity peaks. turns out that patterns sulfur-carbon are nearly identical those carbon, which attributed similar electron density sulfur. Thus, sulfur ideal carbon.
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