Vitamin C Is an Ideal Substitute for Hydrazine in the Reduction of Graphene Oxide Suspensions

作者: M. J. Fernández-Merino , L. Guardia , J. I. Paredes , S. Villar-Rodil , P. Solís-Fernández

DOI: 10.1021/JP100603H

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摘要: The preparation of solution-processable graphene from graphite oxide typically involves a hydrazine reduction step, but the use of such a reagent in the large-scale implementation of this approach is not desirable due to its high toxicity. Here, we compare the deoxygenation efficiency of graphene oxide suspensions by different reductants (sodium borohydride, pyrogallol, and vitamin C, in addition to hydrazine), as well as by heating the suspensions under alkaline conditions. In almost all cases, the degree of reduction attainable and the …

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