Theory of Solutions of Molecules Containing Widely Separated Charges with Special Application to Zwitterions
作者： John G. Kirkwood
DOI: 10.1063/1.1749489
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摘要: The electrical contribution to the chemical potential of an ion having arbitrary charge distribution is calculated with aid Debye‐Huckel theory. calculation based upon a general solution in polar coordinates approximate equation, Δψ—κ2ψ=0. In addition, Born relation between free energy solvation spherical and dielectric constant solvent, generalized include ions distribution. Application theory study influence simple electrolytes, solvent on solubilities aliphatic amino‐acids alcohol water mixtures, discussed.
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