Transesterification‐induced cocrystallization of poly(trimethylene terephthalate) and poly(butylene succinate) blends
作者： Yulan Huang , Le Bao , Yiwang Chen , Weihua Zhou , Licheng Tan
DOI: 10.1002/APP.33122
关键词:
摘要: A series of copolyesters were prepared by the direct melt transesterification poly(trimethylene terephthalate) (PTT) and poly(butylene succinate) (PBS). The sequential structure was analyzed with proton nuclear magnetic resonance spectroscopy, randomness calculated to be approximately 0.8. cocrystallization, thermal behavior, spherulitic morphology investigated. melting points showed a pseudo-eutectic behavior exhibiting isodimorphic cocrystallization. Wide-angle X-ray diffraction indicated that crystallized in PTT crystals when butylene succinate (BS) unit content less than 60% PBS BS greater 70%. mechanical properties greatly influenced sequence lengths aromatic aliphatic units. incorporation units into led faster rate degradation because decrease length increase length. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
sci-hub.se 参考文章(35)
WOJCIECH PISULA, JACEK PIGLOWSKI, CLAUDIA KUMMERLOWE, Preparation and characterization of copolyesters of poly(tetramethylene succinate) and poly(butylene terephthalate) Polimery. ,vol. 51, pp. 341- 350 ,(2006) , 10.14314/POLIMERY.2006.341
Young Gyu Jeong, Won Ho Jo, Sang Cheol Lee, Synthesis and Crystallization Behavior of Poly(m-methylene 2,6-naphthalate-co-1,4-cyclohexylenedimethylene 2,6-naphthalate) Copolymers Macromolecules. ,vol. 36, pp. 4051- 4059 ,(2003) , 10.1021/MA034094J
Laura Mazzocchetti, Mariastella Scandola, Zhaozhong Jiang, Enzymatic Synthesis and Structural and Thermal Properties of Poly(ω-pentadecalactone-co-butylene-co-succinate) Macromolecules. ,vol. 42, pp. 7811- 7819 ,(2009) , 10.1021/MA901338V
F.Ł. Kondratowicz, R. Ukielski, Synthesis and hydrolytic degradation of poly(ethylene succinate) and poly(ethylene terephthalate) copolymers Polymer Degradation and Stability. ,vol. 94, pp. 375- 382 ,(2009) , 10.1016/J.POLYMDEGRADSTAB.2008.12.001
X.Q. Shi, H. Ito, T. Kikutani, Characterization on mixed-crystal structure and properties of poly (butylene adipate-co-terephthalate) biodegradable fibers Polymer. ,vol. 46, pp. 11442- 11450 ,(2005) , 10.1016/J.POLYMER.2005.10.065
GP Karayannidis, CP Roupakias, DN Bikiaris, DS Achilias, None, Study of various catalysts in the synthesis of poly(propylene terephthalate) and mathematical modeling of the esterification reaction Polymer. ,vol. 44, pp. 931- 942 ,(2003) , 10.1016/S0032-3861(02)00875-3
I.J. Desborough, I.H. Hall, J.Z. Neisser, The structure of poly(trimethylene terephthalate) Polymer. ,vol. 20, pp. 545- 552 ,(1979) , 10.1016/0032-3861(79)90163-0
M Nagata, Synthesis and enzymatic degradation of poly(tetramethylene succinate) copolymers with terephthalic acid Polymer. ,vol. 41, pp. 4373- 4376 ,(2000) , 10.1016/S0032-3861(99)00727-2
Faxue Li, Xinjian Xu, Qinghui Hao, Qiaobo Li, Jianyong Yu, Amin Cao, Effects of comonomer sequential structure on thermal and crystallization behaviors of biodegradable poly(butylene succinate‐co‐butylene terephthalate)s Journal of Polymer Science Part B. ,vol. 44, pp. 1635- 1644 ,(2006) , 10.1002/POLB.20797
George Z. Papageorgiou, Dimitris N. Bikiaris, Crystallization and melting behavior of three biodegradable poly(alkylene succinates). A comparative study Polymer. ,vol. 46, pp. 12081- 12092 ,(2005) , 10.1016/J.POLYMER.2005.10.073