New low-dimensional solids: Tellurium-rich alkali metal tellurides

作者: William S. Sheldrick , Michael Wachhold , Stephane Jobic , Raymond Brec , Enric Canadell

DOI: 10.1002/ADMA.19970090818

关键词:

摘要: The crystal and electronic structure of several recently reported tellurium-rich alkali metal tellurides is discussed. Some these materials contain defective square planar tellurium lattices, which on the basis band calculations are expected to be new low-dimensional metals. structural interrelations between some phases can understood once primordial template role as well secondary Te…Te interactions considered. Tellurium-rich seem promising in search for solids with interesting properties.

参考文章(14)
Alain Meerschaut, Jean Rouxel, Pseudo-One-Dimensional MX3 and MX4 Transition Metal Chalcogenides Springer Netherlands. pp. 205- 279 ,(1986) , 10.1007/978-94-009-4528-9_6
W. S. Sheldrick, B. Schaaf, RbTe6, ein Polytellurid mit Schichtstruktur 2∞[Te6-] / RbTe6, a Polytelluride with Layer Structure 2∞[Te6-] Zeitschrift für Naturforschung B. ,vol. 49, pp. 993- 996 ,(1994) , 10.1515/ZNB-1994-0726
Enric Canadell, Ste´phane Jobic, Raymond Brec, Jean Rouxel, Myung-Hwan Whangbo, Importance of short interlayer Te···Te contacts for the structural distortions and physical properties of CdI2-type layered transition-metal ditellurides Journal of Solid State Chemistry. ,vol. 99, pp. 189- 199 ,(1992) , 10.1016/0022-4596(92)90304-E
P. M. Williams, G. S. Parry, C. B. Scrub, Diffraction evidence for the Kohn anomaly in 1T TaS2 Philosophical Magazine. ,vol. 29, pp. 695- 699 ,(1974) , 10.1080/14786437408213248
Peter Böttcher, Tellurium‐Rich Tellurides Angewandte Chemie. ,vol. 27, pp. 759- 772 ,(1988) , 10.1002/ANIE.198807593
Qiang Liu, Norman Goldberg, Roald Hoffmann, A 2,3-Connected Tellurium Net and the Cs3 Te22 Phase Chemistry - A European Journal. ,vol. 2, pp. 390- 397 ,(1996) , 10.1002/CHEM.19960020407
J.A. Wilson, F.J. Di Salvo, S. Mahajan, Charge-density waves and superlattices in the metallic layered transition metal dichalcogenides Advances in Physics. ,vol. 24, pp. 1171- 1248 ,(1975) , 10.1080/00018737500101391
Stephen Lee, Brendan J. Foran, Defective Lattice Charge Density Waves in La10Se19, Cs3Te22, RbDy3Se8, and Dy65.33Se120 Journal of the American Chemical Society. ,vol. 118, pp. 9139- 9147 ,(1996) , 10.1021/JA951965Z