Polylactic acid based molded product and production method therefor

作者: 弘 西村 , Hiroshi Nishimura , Masanobu Hioki , 正信 日置

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摘要: PROBLEM TO BE SOLVED: To provide a polylactic acid based molded product which excels in heat resistance, and enables molding with good productivity the production cycle actual production, method. SOLUTION: A sheet is formed by extruding resin composition containing having content of D- configurational isomer ≤5 mol% an amount residual lactide 0.1-0.6 mass% as major component 1-25 nucleating agent into sheet. Before fabrication or simultaneously fabrication, provided treatment at treating temperature 120-150°C for 1-30 seconds to obtain product. The has thermal properties difference between absolute values quantity crystal fusion ΔHm programmed crystallization ΔHc ≥25 J/g, when measured differential scanning calorimeter under condition programming 20°C/min, crystallinity X-ray measurement ≥35%, rate 130°C ≥0.05 min -1 . COPYRIGHT: (C)2003,JPO

参考文章(9)
弘 西村, 宗博 三宅, Hiroshi Nishimura, Munehiro Miyake, Yoshihiko Tanide, 喜彦 谷出, Biodegradable heat-resistant resin composition, sheet, molded product and foamed product ,(2000)
Masanobu Ajioka, Yasuhiro Kitahara, 正伸 味岡, Kazuhiko Suzuki, Takayuki Watanabe, Tatsuya Kawaguchi, 孝行 渡辺, 泰広 北原, Tomoyuki Nakada, Seiji Obuchi, 智之 中田, 和彦 鈴木, 省二 大淵, 辰也 川口, Production of aliphatic polyester molded product and molded product produced thereby ,(1996)
Hideyuki Furuta, Yasutoshi Kakizawa, 秀幸 古田, 保利 柿澤, Lactate polyester composition and molded product thereof ,(1996)
Jun Takagi, 潤 高木, Biodegradable flexible film ,(2001)
Watanabe Takayuki, Suzuki Kazuhiko, Ajioka Masanobu, Kitahara Yasuhiro, L-LACTIC ACID BASED POLYMER MOLDED FORM AND MANUFACTURE THEREOF ,(1994)
滋憲 寺田, 潤 高木, Shigenori Terada, Jun Takagi, Polylactic acid molding ,(1995)
Yoshida Shigeto, Kobayashi Hisato, Oda Naonobu, METHOD FOR MANUFACTURING LACTIC ACID TYPE POLYESTER BIAXIALLY STRETCHED FILM ,(2003)