Amphiphilic oligoamides as versatile, acid-responsive gelators

作者: Qiang Pei , Quan Tang , Zheng-Li Tan , Zhong-Lin Lu , Lan He

DOI: 10.1039/C7RA03074F

关键词:

摘要: Six oligoamides with the same backbone but different side and end chains, G1–G6, were designed synthesized. Screening gelating abilities of these revealed G2 as a versatile gelator capable forming stable hydrogels well several organogels. From UV, fluorescence, NMR, SEM studies, formation is driven by hydrophobic forces π–π stacking while gelation nonpolar organic solvents relies on hydrogen-bonding interactions. The hydrogel able to encapsulate release medicinally important polar substances into water acid-responsiveness.

参考文章(39)
Fu-Kai Zhan, Shu-Min Hsu, Hsun Cheng, Hsin-Chieh Lin, Remarkable influence of alkyl chain lengths on supramolecular hydrogelation of naphthalene diimide-capped dipeptides RSC Advances. ,vol. 5, pp. 48961- 48964 ,(2015) , 10.1039/C5RA05373K
Motoshi Yamanaka, Yasuhito Miyake, Shigendo Akita, Kazunori Nakano, Sol–Gel Transcription of Semi-Fluorinated Organogel Fiber into Fluorocarbon-Functionalized Silica Nanotubes Chemistry of Materials. ,vol. 20, pp. 2072- 2074 ,(2008) , 10.1021/CM703698P
Huaqiang Zeng, Xiaowu Yang, Robert A. Flowers, Bing Gong, A noncovalent approach to antiparallel β-sheet formation Journal of the American Chemical Society. ,vol. 124, pp. 2903- 2910 ,(2002) , 10.1021/JA010701B
Bing Gong, Yinfa Yan, Huaqiang Zeng, Ewa Skrzypczak-Jankunn, Yong Wah Kim, Jin Zhu, Harold Ickes, A NEW APPROACH FOR THE DESIGN OF SUPRAMOLECULAR RECOGNITION UNITS : HYDROGEN-BONDED MOLECULAR DUPLEXES Journal of the American Chemical Society. ,vol. 121, pp. 5607- 5608 ,(1999) , 10.1021/JA990904O
Bing Gong, Engineering hydrogen-bonded duplexes Polymer International. ,vol. 56, pp. 436- 443 ,(2007) , 10.1002/PI.2175
Xinhua Cao, Jing Zhou, Ying Zou, Mingming Zhang, Xudong Yu, Song Zhang, Tao Yi, Chunhui Huang, Fluorescence and morphology modulation in a photochromic diarylethene self-assembly system. Langmuir. ,vol. 27, pp. 5090- 5097 ,(2011) , 10.1021/LA200419V
Ruikai Cao, Jingjing Zhou, Wei Wang, Wen Feng, Xianghui Li, Penghui Zhang, Pengchi Deng, Lihua Yuan, Bing Gong, Oligoamide duplexes as organogelators Organic Letters. ,vol. 12, pp. 2958- 2961 ,(2010) , 10.1021/OL100953E
Huaqiang Zeng, Rebecca S. Miller, Robert A. Flowers, Bing Gong, A Highly Stable, Six-Hydrogen-Bonded Molecular Duplex Journal of the American Chemical Society. ,vol. 122, pp. 2635- 2644 ,(2000) , 10.1021/JA9942742
Jamie R. Moffat, David K. Smith, Controlled self-sorting in the assembly of ‘multi-gelator’ gels Chemical Communications. pp. 316- 318 ,(2009) , 10.1039/B818058J
Zaiwu Yuan, Weijie Lu, Weimin Liu, Jingcheng Hao, Gel phase originating from molecular quasi-crystallization and nanofiber growth of sodium laurate–water system Soft Matter. ,vol. 4, pp. 1639- 1644 ,(2008) , 10.1039/B804157A