Microwave-assisted synthesis and characterization of the monomeric phthalocyanines containing naphthalene-amide group moieties and the polymeric phthalocyanines containing oxa-aza bridge
作者： Musa Özil , Erbil Ağar , Selami Şaşmaz , Bahittin Kahveci , Nesuhi Akdemir
DOI: 10.1016/J.DYEPIG.2006.07.026
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摘要: Abstract New naphthalene-amide substituted phthalocyanines and oxa-aza bridge polymeric were prepared by conventional microwave methods. The chlorides of Cu(I), Ni(II) Co(II) employed in order to synthesize the corresponding metal Zn(CH 3 COO) 2 was used for preparation zinc phthalocyanines. For Co-containing phthalocyanines, ammonium molybdate had be added as catalyst. In microwave-assisted synthesis, DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) or DMAE (dimethylaminoethanol) a solvent. solubility containing group ( 1a – e , 3a ) is low ethanol, ethyl acetate, chloroform, DMF DMSO. Polymeric 2a are not soluble common organic solvents such DMSO but dilute H SO 4 .
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