The relations between relaxation spectra, flaw growth, and ultimate properties of PVC

作者: W. Retting

DOI: 10.1016/0014-3057(70)90009-1

关键词:

摘要: Abstract Firstly a short survey is given of the phenomenological relations between ultimate properties and relaxation spectra polymers. It turned out that in many cases temperature-time positions brittle-tough transitions agree quite well with those certain maxima. Further, it demonstrated (in particular extensibility polymers) are essentially determined by growth flaws. A description an indirect method to examine average flaw during tensile tests. By means this method, shown case PVC secondary (short time low temperature) mechanisms cause first transition diminution macroscopic stress. second occurs when microscopic notch stresses diminished main (long high mechanism.

参考文章(10)
Adolf Smekal, Die Festigkeitseigenschaften spröder Körper ErNW. ,vol. 15, pp. 106- 188 ,(1936) , 10.1007/BFB0111967
F. Bueche, J. C. Halpin, Molecular Theory for the Tensile Strength of Gum Elastomers Journal of Applied Physics. ,vol. 35, pp. 36- 41 ,(1964) , 10.1063/1.1713095
Roy C. Laible, Henry M. Morgan, The viscoelastic behavior of isotactic polypropylene fibers Journal of Applied Polymer Science. ,vol. 6, pp. 269- 277 ,(1962) , 10.1002/APP.1962.070062104
Ad. Engelter, F. H. Müller, Thermische Effekte bei mechanischer Deformation, insbesondere von Hochpolymeren Colloid and Polymer Science. ,vol. 157, pp. 89- 111 ,(1958) , 10.1007/BF01740139
W. Retting, Beeinflussung des Bruchverhaltens von Hochpolymeren durch molekulare Relaxationsprozesse Kolloid-Zeitschrift & Zeitschrift für Polymere. ,vol. 213, pp. 69- 79 ,(1966) , 10.1007/BF01552515
I. H. Hall, Temperature–strain rate transformations with isotactic polypropylene at finite strains Journal of Applied Polymer Science. ,vol. 8, pp. 1577- 1581 ,(1964) , 10.1002/APP.1964.070080407
R. F. Boyer, Dependence of mechanical properties on molecular motion in polymers Polymer Engineering and Science. ,vol. 8, pp. 161- 185 ,(1968) , 10.1002/PEN.760080302