Phosphorus Partition between Liquid Steel and CaO-SiO 2 -FeO x -P 2 O 5 -MgO Slag Containing 15 to 25 Pct FeO
作者： Somnath Basu , Ashok Kumar Lahiri , Seshadri Seetharaman
DOI: 10.1007/S11663-007-9063-0
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摘要: CaO-SiO2-FeO x -P2O5-MgO bearing slags are typically used in the basic oxygen steelmaking (BOS) process. The partition ratio of phosphorus between slag and steel is an index holding capacity slag, which determines content achievable finished steel. influence factors such as FeO basicity on was investigated at two different temperatures. initially increased with but remained constant beyond a 2.5 to 2.6. An increase up 18 20 mass pct beneficial for level 2 3, higher concentration resulted decrease ratio; corresponding this transition varied temperature. At even lower basicities, however, equilibrium showed either no change, or marginally decreasing trend, content.
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E. T. Turkdogan, Fundamentals of steelmaking ,(1996)
Shiro Ban-Ya, Mathematical Expression of Slag-Metal Reactions in Steelmaking Process by Quadratic Formalism Based on the Regular Solution Model Isij International. ,vol. 33, pp. 2- 11 ,(1993) , 10.2355/ISIJINTERNATIONAL.33.2
G. K. Sigworth, J. F. Elliott, The Thermodynamics of Liquid Dilute Iron Alloys Metal science. ,vol. 8, pp. 298- 310 ,(1974) , 10.1179/MSC.1974.8.1.298
Hideaki SUITO, Ryo INOUE, Minoru TAKADA, Phosphorus Distribution between Liquid Iron and MgO Saturated Slags of the System CaO-MgO-FeOx-SiO2 Isij International. ,vol. 21, pp. 250- 259 ,(1981) , 10.2355/ISIJINTERNATIONAL1966.21.250
E. T. Turkdogan, Assessment of P2O5 Activity Coefficients in Molten Slags Isij International. ,vol. 40, pp. 964- 970 ,(2000) , 10.2355/ISIJINTERNATIONAL.40.964
M. Hasegawa, M. Iwase, K. Wakimoto, A. McLean, A thermochemical study of the CaO + P2O5+ FexO system—regions in equilibrium with solid Ca3P2O8 Scandinavian Journal of Metallurgy. ,vol. 32, pp. 47- 52 ,(2003) , 10.1034/J.1600-0692.2003.10610.X
Ping Zhang, Seshadri Seetharaman, Dissolution of MgO in CaO–“FeO”–CaF2–SiO2 Slags under Static Conditions Journal of the American Ceramic Society. ,vol. 77, pp. 970- 976 ,(1994) , 10.1111/J.1151-2916.1994.TB07254.X
Carl Wagner, The activity coefficient of oxygen and other nonmetallic elements in binary liquid alloys as a function of alloy composition Acta Metallurgica. ,vol. 21, pp. 1297- 1303 ,(1973) , 10.1016/0001-6160(73)90171-5
Jeoungkiu Im, Kazuki Morita, Nobuo Sano, Phosphorus Distribution Ratios between CaO-SiO2-FetO Slags and Carbon-saturated Iron at 1573 K Isij International. ,vol. 36, pp. 517- 521 ,(1996) , 10.2355/ISIJINTERNATIONAL.36.517