Ultrathin Laminar Ir Superstructure as Highly Efficient Oxygen Evolution Electrocatalyst in Broad pH Range

作者: Yecan Pi , Nan Zhang , Shaojun Guo , Jun Guo , Xiaoqing Huang

DOI: 10.1021/ACS.NANOLETT.6B01554

关键词:

摘要: Shape-controlled noble metal nanocrystals (NCs), such as Au, Ag, Pt, Pd, Ru, and Rh are of great success due to their new and enhanced properties and applications in chemical conversion, fuel cells, and sensors, but the realization of shape control of Ir NCs for achieving enhanced electrocatalysis remains a significant challenge. Herein, we report an efficient solution method for a new class of three-dimensional (3D) Ir superstructure that consists of ultrathin Ir nanosheets as subunits. Electrochemical studies show that it delivers …

参考文章(35)
Li Zhao, Chaofa Xu, Haifeng Su, Jinghong Liang, Shuichao Lin, Lin Gu, Xingli Wang, Mei Chen, Nanfeng Zheng, None, Single‐Crystalline Rhodium Nanosheets with Atomic Thickness Advanced Science. ,vol. 2, pp. 1500100- ,(2015) , 10.1002/ADVS.201500100
Michael G. Walter, Emily L. Warren, James R. McKone, Shannon W. Boettcher, Qixi Mi, Elizabeth A. Santori, Nathan S. Lewis, Solar Water Splitting Cells Chemical Reviews. ,vol. 110, pp. 6446- 6473 ,(2010) , 10.1021/CR1002326
Micaela Crespo-Quesada, Jean-Michel Andanson, Artur Yarulin, Byungkwong Lim, Younan Xia, Lioubov Kiwi-Minsker, UV–Ozone Cleaning of Supported Poly(vinylpyrrolidone)-Stabilized Palladium Nanocubes: Effect of Stabilizer Removal on Morphology and Catalytic Behavior Langmuir. ,vol. 27, pp. 7909- 7916 ,(2011) , 10.1021/LA201007M
Haohong Duan, Ning Yan, Rong Yu, Chun-Ran Chang, Gang Zhou, Han-Shi Hu, Hongpan Rong, Zhiqiang Niu, Junjie Mao, Hiroyuki Asakura, Tsunehiro Tanaka, Paul Joseph Dyson, Jun Li, Yadong Li, Ultrathin rhodium nanosheets Nature Communications. ,vol. 5, pp. 3093- ,(2014) , 10.1038/NCOMMS4093
Sehkyu Park, Yuyan Shao, Jun Liu, Yong Wang, Oxygen Electrocatalysts for Water Electrolyzers and Reversible Fuel Cells: Status and Perspective Energy and Environmental Science. ,vol. 5, pp. 9331- 9344 ,(2012) , 10.1039/C2EE22554A
Hee Sung Lee, Sung-Wook Min, Youn-Gyung Chang, Min Kyu Park, Taewook Nam, Hyungjun Kim, Jae Hoon Kim, Sunmin Ryu, Seongil Im, MoS2 Nanosheet Phototransistors with Thickness-Modulated Optical Energy Gap Nano Letters. ,vol. 12, pp. 3695- 3700 ,(2012) , 10.1021/NL301485Q
Shaojun Guo, Sen Zhang, Shouheng Sun, Tuning Nanoparticle Catalysis for the Oxygen Reduction Reaction Angewandte Chemie. ,vol. 52, pp. 8526- 8544 ,(2013) , 10.1002/ANIE.201207186
Lena Trotochaud, James K. Ranney, Kerisha N. Williams, Shannon W. Boettcher, Solution-cast metal oxide thin film electrocatalysts for oxygen evolution. Journal of the American Chemical Society. ,vol. 134, pp. 17253- 17261 ,(2012) , 10.1021/JA307507A
Youngmin Lee, Jin Suntivich, Kevin J. May, Erin E. Perry, Yang Shao-Horn, Synthesis and Activities of Rutile IrO2 and RuO2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions Journal of Physical Chemistry Letters. ,vol. 3, pp. 399- 404 ,(2012) , 10.1021/JZ2016507
Marcelo Carmo, David L. Fritz, Jürgen Mergel, Detlef Stolten, A comprehensive review on PEM water electrolysis International Journal of Hydrogen Energy. ,vol. 38, pp. 4901- 4934 ,(2013) , 10.1016/J.IJHYDENE.2013.01.151