Comparative potential of black tea leaves waste to granular activated carbon in adsorption of endocrine disrupting compounds from aqueous solution

作者: A.O. Ifelebuegu , J. E. Ukpebor , C. C. Obidiegwu , B. C. Kwofi , None

DOI: 10.7508/GJESM.2015.03.003

关键词:

摘要: The adsorption properties and mechanics of selected endocrine disrupting compounds; 17 β-estradiol, α – ethinylestradiol bisphenol A on locally available black tea leaves waste granular activated carbon were investigated. results obtained indicated that the kinetics pH, adsorbent dose, contact time temperature dependent with equilibrium being reached at 20 to 40 minutes for 60 compound. Maximum capacities 3.46, 2.44 18.35 mg/g achieved compared compound 4.01, 2.97 16.26 β- estradiol, α-ethinylestradiol respectively. Tea followed pseudo-first order while fitted better pseudo-second kinetic model. experimental isotherm data both showed a good fit Langmuir, Freundlich Temkin models Langmuir model showing best fit. thermodynamic process was predominantly by physical more chemical in nature. have demonstrated potential adsorptive removal compounds from water.

参考文章(29)
A Yoshita, JH Ye, YR Liang, JL Lu, Sorption of lead from aqueous solutions by spent tea leaf African Journal of Biotechnology. ,vol. 8, pp. 2212- 2217 ,(2009) , 10.4314/AJB.V8I10.60558
Robert Ewald Treybal, Mass-transfer operations ,(1955)
Dana W. Kolpin, Edward T. Furlong, Michael T. Meyer, E. Michael Thurman, Steven D. Zaugg, Larry B. Barber, Herbert T. Buxton, Response to Comment on “Pharmaceuticals, Hormones, and Other Organic Wastewater Contaminants in U.S. Streams, 1999−2000: A National Reconnaissance” Environmental Science & Technology. ,vol. 36, pp. 1054- 1054 ,(2002) , 10.1021/ES020136S
Yeomin Yoon, Jaena Ryu, Jeill Oh, Byeong-Gyu Choi, Shane A. Snyder, Occurrence of endocrine disrupting compounds, pharmaceuticals, and personal care products in the Han River (Seoul, South Korea). Science of The Total Environment. ,vol. 408, pp. 636- 643 ,(2010) , 10.1016/J.SCITOTENV.2009.10.049
V. Cases, V. Alonso, V. Argandoña, M. Rodriguez, D. Prats, Endocrine disrupting compounds: A comparison of removal between conventional activated sludge and membrane bioreactors Desalination. ,vol. 272, pp. 240- 245 ,(2011) , 10.1016/J.DESAL.2011.01.026
Augustine O. Ifelebuegu, Removal of Steriod Hormones by Activated Carbon Adsorption—Kinetic and Thermodynamic Studies Journal of Environmental Protection. ,vol. 3, pp. 469- 475 ,(2012) , 10.4236/JEP.2012.36057
M. Ghaedi, A.M. Ghaedi, E. Negintaji, A. Ansari, A. Vafaei, M. Rajabi, Random forest model for removal of bromophenol blue using activated carbon obtained from Astragalus bisulcatus tree Journal of Industrial and Engineering Chemistry. ,vol. 20, pp. 1793- 1803 ,(2014) , 10.1016/J.JIEC.2013.08.033
Isil Gültekin, Nilsun H. Ince, Synthetic endocrine disruptors in the environment and water remediation by advanced oxidation processes. Journal of Environmental Management. ,vol. 85, pp. 816- 832 ,(2007) , 10.1016/J.JENVMAN.2007.07.020
Yanping Zhang, John L. Zhou, Removal of estrone and 17β-estradiol from water by adsorption Water Research. ,vol. 39, pp. 3991- 4003 ,(2005) , 10.1016/J.WATRES.2005.07.019
Yuh-Shan Ho, Gordon McKay, SORPTION OF DYE FROM AQUEOUS SOLUTION BY PEAT Chemical Engineering Journal. ,vol. 70, pp. 115- 124 ,(1998) , 10.1016/S0923-0467(98)00076-1