1,7-Electrocyclisation of non-stabilised azomethine ylides

作者: Andrea Arany , Paul W. Groundwater , Miklòs Nyerges

DOI: 10.1016/S0040-4039(98)00466-3

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摘要: Abstract Non-stablilised α,β;γ,δ-unsaturated azomethine ylides 3 were generated by the decarboxylation method from 3,3-diarylpropenals 1 and secondary amino acids 2 . 1,7-Electrocyclisation of these ylides, followed a 1,5-hydrogen shift, gives 2,3-dihydro-1 H -2-benzazephines 4

参考文章(2)
Miklós Nyerges, László Balázs, István Kádas, István Bitter, István Kövesdi, László To&̋ke, trans-3-Aryl-4-nitro-pyrrolidines via 1,3-dipolar cycloaddition of nonstabilized azomethine ylide to ß-nitro styrenes Tetrahedron. ,vol. 51, pp. 6783- 6788 ,(1995) , 10.1016/0040-4020(95)00311-U