Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst
作者： Christian Schumacher , Deborah E. Crawford , Branimir Raguž , Robert Glaum , Stuart L. James
DOI: 10.1039/C8CC04487B
关键词:
摘要: Mechanochemistry enabled the selective synthesis of recherche orange polymorph Wilkinson's catalyst [RhCl(PPh3)3]. The mechanochemically prepared Rh-complex catalysed solvent-free dehydrogenation Me2NH·BH3 in a ball mill. situ-generated hydrogen (H2) could be utilised for Rh-catalysed hydrogenation reactions by milling.
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sci-hub.se 参考文章(60)
Viktor P. Balema, Jerzy W. Wiench, Marek Pruski, Vitalij K. Pecharsky, Solvent-free mechanochemical synthesis of two Pt complexes: cis-(Ph3P)2PtCl2 and cis-(Ph3P)2PtCO3. Chemical Communications. pp. 1606- 1607 ,(2002) , 10.1039/B203694K
José G. Hernández, Carsten Bolm, [Cp*RhCl2]2: mechanosynthesis and applications in C-H bond functionalisations under ball-milling conditions. Chemical Communications. ,vol. 51, pp. 12582- 12584 ,(2015) , 10.1039/C5CC04423E
M. Reza Naimi-Jamal, Javad Mokhtari, Mohammad G. Dekamin, Gerd Kaupp, Sodium Tetraalkoxyborates: Intermediates for the Quantitative Reduction of Aldehydes and Ketones to Alcohols through Ball Milling with NaBH4 European Journal of Organic Chemistry. ,vol. 2009, pp. 3567- 3572 ,(2009) , 10.1002/EJOC.200900352
Matthew E. Sloan, Anne Staubitz, Kajin Lee, Ian Manners, Scope and Selectivity of Heterogeneous Rh0-Catalyzed Tandem Dehydrocoupling/Hydrogenation Using Me2NH·BH3 as a Stoichiometric H2 Source European Journal of Organic Chemistry. ,vol. 2011, pp. 672- 675 ,(2011) , 10.1002/EJOC.201001332
Michael J. Bennett, Peter B. Donaldson, Crystal and molecular structure of the orange and red allotropes of chlorotris(triphenylphosphine)rhodium(I) Inorganic Chemistry. ,vol. 16, pp. 655- 660 ,(1977) , 10.1021/IC50169A033
José G. Hernández, Ian S. Butler, Tomislav Friščić, Multi-step and multi-component organometallic synthesis in one pot using orthogonal mechanochemical reactions Chemical Science. ,vol. 5, pp. 3576- 3582 ,(2014) , 10.1039/C4SC01252F
Cory A. Jaska, Karen Temple, Alan J. Lough, Ian Manners, Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines Journal of the American Chemical Society. ,vol. 125, pp. 9424- 9434 ,(2003) , 10.1021/JA030160L
Daniel Fürniss, Ute Schepers, Stefan Bräse, Killing double bonds softly: the reduction of polymer-bound alkenes RSC Advances. ,vol. 2, pp. 11273- 11278 ,(2012) , 10.1039/C2RA22189F
John A Osborn, FH Jardine, J Francis Young, Geoffrey Wilkinson, None, The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives Journal of the Chemical Society A: Inorganic, Physical, Theoretical. pp. 1711- 1732 ,(1966) , 10.1039/J19660001711
Marina Juribašić, Krunoslav Užarević, Davor Gracin, Manda Ćurić, Mechanochemical C–H bond activation: rapid and regioselective double cyclopalladation monitored by in situ Raman spectroscopy Chemical Communications. ,vol. 50, pp. 10287- 10290 ,(2014) , 10.1039/C4CC04423A