Broadband down-conversion through the co-contribution of simultaneous energy transfer from Eu3+/2+ to Yb3+ and CTS absorption of Yb3+

作者: Huiyun Wang , Song Ye , Song Li , Tianhua Liu , Jian Lin

DOI: 10.1016/J.JALLCOM.2015.05.241

关键词:

摘要: Abstract The europium (Eu) and ytterbium (Yb) co-doped SiO2–Al2O3–MF2 (M = Ca, Sr) oxyfluoride glasses were prepared by the melting-quenching method, in which partial reduction of Eu3+ ions during high temperature fabrication air atmosphere was explained optical basicity model. In this system, near-infrared emission Yb3+ at 974 nm can be observed upon excitation both Eu2+, as well charge transfer state absorption Yb3+. steady time-resolved luminescence spectra measurements carried out to further prove energy from Eu3+/2+ Based on measured decay efficiency quantum are much higher glass containing SrF2 due efficient Eu2+

参考文章(27)
Song Ye, Bin Zhu, Jingxin Chen, Jin Luo, Jian Rong Qiu, Infrared quantum cutting in Tb3+,Yb3+ codoped transparent glass ceramics containing CaF2 nanocrystals Applied Physics Letters. ,vol. 92, pp. 141112- ,(2008) , 10.1063/1.2907496
W. S. Tsang, W. M. Yu, C. L. Mak, W. L. Tsui, K. H. Wong, H. K. Hui, Evidence of the influence of phonon density on Tm3+ upconversion luminescence in tellurite and germanate glasses Journal of Applied Physics. ,vol. 91, pp. 1871- 1874 ,(2002) , 10.1063/1.1429762
Morten M. Smedskjaer, Jianrong Qiu, John Wang, Yuanzheng Yue, Near-Infrared Emission from Eu-Yb Doped Silicate Glasses Subjected to Thermal Reduction Applied Physics Letters. ,vol. 98, pp. 071911- ,(2011) , 10.1063/1.3556316
Kaushik Biswas, Sathravada Balaji, Debarati Ghosh, Atul D. Sontakke, Kalyandurg Annapurna, Near-infrared frequency down-conversion and cross-relaxation in Eu2+/Eu3+–Yb3+ doped transparent oxyfluoride glass and glass–ceramics Journal of Alloys and Compounds. ,vol. 608, pp. 266- 271 ,(2014) , 10.1016/J.JALLCOM.2014.04.126
Q.Y. Zhang, X.Y. Huang, Recent progress in quantum cutting phosphors Progress in Materials Science. ,vol. 55, pp. 353- 427 ,(2010) , 10.1016/J.PMATSCI.2009.10.001
S.A.M. Abdel-Hameed, N.A. Ghoniem, E.A. Saad, F.H. Margha, Effect of fluoride ions on the preparation of transparent glass ceramics based on crystallization of barium borates Ceramics International. ,vol. 31, pp. 499- 505 ,(2005) , 10.1016/J.CERAMINT.2004.05.028
Hang Lin, Daqin Chen, Yunlong Yu, Zhifa Shan, Ping Huang, Anping Yang, Yuansheng Wang, Broadband UV excitable near-infrared downconversion luminescence in Eu2+/Yb3+:CaF2 nanocrystals embedded glass ceramics Journal of Alloys and Compounds. ,vol. 509, pp. 3363- 3366 ,(2011) , 10.1016/J.JALLCOM.2010.12.066
Nan Jiang, Local order of Ca in a CaF2–Al2O3–SiO2 glass by electron energy-loss spectroscopy Journal of Applied Physics. ,vol. 110, pp. 013518- ,(2011) , 10.1063/1.3608118
Yu Teng, Jiajia Zhou, Xiaofeng Liu, Song Ye, Jianrong Qiu, Efficient broadband near-infrared quantum cutting for solar cells. Optics Express. ,vol. 18, pp. 9671- 9676 ,(2010) , 10.1364/OE.18.009671