Theory of Some van der Waals Molecules

摘要: Using a potential function of the form V(R)=A(ρ)e−R/ρ−c1R6−c2R8−c3R10−c4R12, vibrational wave number and energy dissociation molecules HgHe, HgNe, HgA, HgKr, HgXe, Hg2, (O2)2 (NO)2 in normal state are calculated. It is found that, if single value ρ=0.28A chosen, satisfactory agreement obtained with experimental data except case (NO)2. The latter structure believed to owe its binding partly first‐order attractive forces.