Liquid−liquid extraction of trivalent actinides and lanthanides with 1-phenyl-3-methyl-4-trifluoroacetyl pyrazolone-5

作者: J.N. Mathur , P.K. Khopkar

DOI: 10.1016/S0277-5387(00)84271-0

关键词:

摘要: Abstract Extraction of the trivalent actinides Am, Cm and Cf lanthanides Eu, Tb, Tm Lu has been studied with 1-phenyl-3-methyl-4-trifluoroacetyl pyrazolone- 5(HPMTFP) in chloroform benzene. The formation a self-adduct species M(PMTFP)3·HPMTFP observed Eu but only chelate M(PMTFP)3 Cf, Lu. reasons for lighter not heavier ones pyrazolones have discussed.

参考文章(13)
J.H. Matnur, P.K. Khopkax, TBITALEBT ACTINTDES AND LAHTHANIDES USING 1-PHENEYL-3METHYL-4BENZOYL-PYRAZOLONE-5(HPMBP) Solvent Extraction and Ion Exchange. ,vol. 1, pp. 597- 606 ,(1983) , 10.1080/07366298308918418
Yoshimi Sasaki, Henry Freiser, Mixed-ligand chelate extraction of lanthanides with 1-phenyl-3-methyl-4-acyl-5-pyrazolones Inorganic Chemistry. ,vol. 22, pp. 2289- 2292 ,(1983) , 10.1021/IC00158A014
Bror Skytte Jensen, Hans Meier, Knut Lundquist, Susanne Refn, THE SYNTHESIS OF 1-PHENYL-3-METHYL-4-ACYL-PYRAZOLONES-5 Acta Chemica Scandinavica. ,vol. 13, pp. 1668- 1670 ,(1959) , 10.3891/ACTA.CHEM.SCAND.13-1668
T. Hori, M. Kawashima, H. Freiser, Mixed ligand chelate extraction of lanthanides I. 8-quinolinol systems Separation Science and Technology. ,vol. 15, pp. 861- 875 ,(1980) , 10.1080/01496398008076275
Huang Chun-Hui⊃1, Henry Freiser, THE EXTRACTION OF LANTHANIDES WITH HALOGEN SUBSTITUTED 4-ACYL-PYRAZOLONES Solvent Extraction and Ion Exchange. ,vol. 4, pp. 41- 59 ,(1986) , 10.1080/07366298608917852
P. K. Khopkar, J. N. Mathur, Synergistic extraction of trivalent Am, Cm, Bk and Cf with HTTA+TBP in xylene Journal of Radioanalytical and Nuclear Chemistry. ,vol. 60, pp. 131- 140 ,(1980) , 10.1007/BF02518290
P.K. Khopkar, J.N. Mathur, Synergistic extraction of some trivalent actinides and lanthanides by thenoyltrifluoroacetone and aliquat chloride Journal of Inorganic and Nuclear Chemistry. ,vol. 39, pp. 2063- 2067 ,(1977) , 10.1016/0022-1902(77)80548-4
J. N. Mathur, Synergism of trivalent actinides and lanthanides Solvent Extraction and Ion Exchange. ,vol. 1, pp. 349- 412 ,(1983) , 10.1080/07366298308918406