On the Effect of 1,2-Disubstitution with Me3M (M = Si, Ge, Sn) Groups upon the Electronic Structure of 3,3-Dimethylcyclopropene
作者： Mirjana Eckert-Maksic , Susanne Elbel , Michael Stohlmeier , Sven Untiedt , Armin de Meijere
关键词:
摘要: He(I) PE spectra of a series 3,3-dimethylcyclopropenes bearing Me3Si (1), Me3Ge (2), and Me3Sn (3) groups in the 1- 2-positions, as well He(II) 1 3 were recorded. The changes lowest energy ionizations along are interpreted terms inductive hy-perconjugative interactions. new compounds prepared by reaction lithiated 3,3-dimethylcyclopropene with corresponding trimethylmetal chlorides.
sci-hub.se 参考文章(48)
Michael James Steuart Dewar, Ralph C. Dougherty, The PMO Theory of Organic Chemistry ,(1975)
Kenneth King, Harold Kwart, d-Orbitals in the Chemistry of Silicon, Phosphorus and Sulfur ,(1977)
H. Bock, B. Solouki, Photoelectron Spectra of Silicon Compounds John Wiley & Sons, Ltd. pp. 555- 653 ,(2004) , 10.1002/0470025107.CH9
A. Schewig, U. Weidner, G. Manuel, Theory and application of photoelectron spectroscopy : XVI. Photoelectron spectroscopy and molecular conformations: GeC and SnC hyperconjugation and the conformation of allygermanes and -stannanes Journal of Organometallic Chemistry. ,vol. 54, pp. 145- 148 ,(1973) , 10.1016/S0022-328X(00)85002-0
P.K. Bischof, M.J.S. Dewar, D.W. Goodman, T.B. Jones, Photoelectron spectra of molecules—IV Journal of Organometallic Chemistry. ,vol. 82, pp. 89- 98 ,(1970) , 10.1016/S0022-328X(00)80723-8
W. Weyrich, E. Heilbronner und H. Bock: Das HMO‐Modell und seine Anwendung. 3 Bände (I: Grundlagen und Handhabung, II: Übungsbeispiele mit Lösungen, III: Tabellen berechneter und experimenteller Gröβen), Verlag Chemie, Weinheim/Bergstr. 1968 ‐ 1970, 404 + 452 + 270 Seiten. Brosch. DM 99,‐. Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 76, pp. 369- 370 ,(1972) , 10.1002/BBPC.19720760357
T Koopmans, Über die Zuordnung von Wellenfunktionen und Eigenwerten zu den Einzelnen Elektronen Eines Atoms Physica D: Nonlinear Phenomena. ,vol. 1, pp. 104- 113 ,(1934) , 10.1016/S0031-8914(34)90011-2
H. Bock, H. Seidl, Ionisierungsenergien von Silyl- und Alkyl-äthylenen† Angewandte Chemie. ,vol. 79, pp. 1106- 1107 ,(1967) , 10.1002/ANGE.19670792413
M. Eckert-Maksić, Mirta Golić, Ljiljana Paša-Tolić, Photoelectron spectroscopic study of novel Group 14 functionalized vinylcyclopropenes Journal of Organometallic Chemistry. ,vol. 489, pp. 35- 41 ,(1995) , 10.1016/0022-328X(94)05149-6
Robin Walsh, Sven Untiedt, Armin De Meijere, Gas‐Phase Kinetics of the Pyrolysis of Some 3,3‐Dimethyl‐1‐(trimethylsilyl)‐cyclopropenes — Unexpected Product Distribution in the Cyclopropene Rearrangement Chemische Berichte. ,vol. 127, pp. 237- 245 ,(1994) , 10.1002/CBER.19941270134