Catalytic activity of nickel polyphthalocyanine in the reduction of nitric oxide with hydrogen
作者： Isao Mochida , Takashi Miyaishi , Harunori Goshi , Hiroshi Fujitsu , Kenjiro Takeshita
DOI: 10.1016/0166-9834(83)80008-6
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摘要: Abstract The catalytic activity of nickel polyphthalocyanine for the reduction nitric oxide with hydrogen was studied in comparison that monomeric phthalocyanine to reveal influence polyconjugation on activation ability phthalocyanines respect and hydrogen. polymeric exhibited a stable considerable at low reaction temperature, where principal product varied from nitrous ammonia, depending temperature. polymer could adsorb as well spite its fun occupation d-orbitals central metal ion. Nitric revealed by FT-IR be adsorbed activated bent form. Based an extended kinetic study, plausible scheme this is proposed.
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