Diastereoselective Synthesis of Enantiopure Acyclic β,β′-Disubstituted Vinylsulfoxides
作者： Franck Brebion , Jean-Philippe Goddard , Louis Fensterbank , Max Malacria
DOI: 10.1021/OL800368G
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摘要: Thermal elimination of sulfenic acid from enantiopure β,β′-disubstituted bis-sulfoxides allows the stereoselective synthesis acyclic vinylsulfoxides. This mild and stereospecific provides either (E) or (Z) vinylsulfoxides in high yields is compatible with base sensitive functional groups.
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