Mise en evidence de la formation de R2MMR2 a partir de disila-1,2 et digerma-1,2 cyclohexenes-4
作者： Annette Marchand , Pierre Gerval , Françoise Duboudin , M.-H. Gaufryau , Marguerite Joanny
DOI: 10.1016/0022-328X(84)80162-X
关键词:
摘要: Abstract Intermediates with π-bonded Si or Ge are generated during gas phase pyrolysis of 1,2-disila- 1,2-digerma-cyclohex-4-enes. Compounds such as R2MMR2 successfully trapped by addition [2 + 2] and [4 cycloadditions. These results were proved mass spectrometry.
elsevier.com
sci-hub.se 参考文章(48)
Yasuhiro Nakadaira, Yoshiteru Kobayashi, Hideki Sakurai, Mass spectroscopy of organosilicon compounds Journal of Organometallic Chemistry. ,vol. 63, pp. 79- 83 ,(1973) , 10.1016/S0022-328X(73)80020-8
Friedrich H�fler, Schwingungsspektren und Kraftkonstanten von Hexamethyldisilan, Hexaphenyldisilan und 1,1,1-Trimethyl-2,2,2-triphenyldisilan Monatshefte Fur Chemie. ,vol. 107, pp. 893- 906 ,(1976) , 10.1007/BF00904476
Annette Marchand, Pierre Gerval, Marguerite Joanny, Pierre Mazerolles, Spectres de vibration de composes organiques des elements de la colonne IVb: XIII. Etude physico-chimique par spectrometries rmn, infrarogue et raman de disila-1,2 et digerma-1,2 cyclohexenes-4 et digerma-1,2 cycloalcanes☆ Journal of Organometallic Chemistry. ,vol. 217, pp. 19- 33 ,(1981) , 10.1016/S0022-328X(00)86019-2
A. Marchand, A. Millan, J. Dunogues, G. Manuel, P. Mazerolles, Spectres de vibration de composes organiques des elements de la colonne IVB : X. Sila-1 et germa-1 cyclopentenes-3☆ Journal of Organometallic Chemistry. ,vol. 135, pp. 23- 37 ,(1977) , 10.1016/S0022-328X(00)91688-7
N. Auner, J. Grobe, Silaethene : IV. Gasphasenpyrolyse von cyclopentadienyl-monosilacyclobutanen Journal of Organometallic Chemistry. ,vol. 190, pp. 129- 145 ,(1980) , 10.1016/S0022-328X(00)85911-2
William D. Wulff, William F. Goure, Thomas J. Barton, The role of trimethylsilylmethylsilylene in the gas-phase reactions of tetramethyldisilene Journal of the American Chemical Society. ,vol. 100, pp. 6236- 6238 ,(1978) , 10.1021/JA00487A049
Iain M.T. Davidson, Naaman A. Ostah, Dietmar Seyferth, Don P. Duncan, A gas kinetic study of the pyrolysis of octamethyl-1,2-disilacyclobutane Journal of Organometallic Chemistry. ,vol. 187, pp. 297- 304 ,(1980) , 10.1016/S0022-328X(00)93422-3
P. Mazerolles, M. Lesbre, Mme M. Joanny, Synthèse et réactivité comparée de 1,2-digermacycloalcanes à cinq et six chaînons Journal of Organometallic Chemistry. ,vol. 16, pp. 227- 233 ,(1969) , 10.1016/S0022-328X(00)81110-9
Mark R. Hoffmann, Yasunori Yoshioka, Henry F. Schaefer, Vibrational frequencies for silaacetylene and its silylidene and vinylidene isomers Journal of the American Chemical Society. ,vol. 105, pp. 1084- 1088 ,(1983) , 10.1021/JA00343A002
V. Yu. Orlov, L. E. Gusel'nikov, N. S. Nametkin, R. L. Ushakova, Mass spectra of methylsubstituted monosila- and monogermacyclobutanes, 1,2- disila- and 1,2-digermacyclopentanes. Some correlations with thermal decomposition Organic Mass Spectrometry. ,vol. 6, pp. 309- 316 ,(1972) , 10.1002/OMS.1210060309