Carbon monoxide transfer to a metal co-ordinated carbyne ligand: X-ray crystal structure of [Mn2{µ-C(CO)C6H4-Me-p}(CO)6(η-C5H5)]·0·5Et2O

作者： Jesús Martin-Gil , Judith A. K. Howard , Rafael Navarro , F. Gordon A. Stone

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摘要: The mononuclear cationic carbyne complexes [MC·C6H4Me-p-(CO)2(η-C5H5)]BF4(M = Mn or Re) react with [(Ph3P)2N][Mn(CO)5] to give compounds [MMn{µ-C(CO)·C6H4Me-p}(CO)6(η-C5H5)]·0·5Et2O in which a CO ligand has transferred the bridging group; structure of dimanganese compound been established by X-ray crystallography.

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Carbon monoxide transfer to a metal co-ordinated carbyne ligand: X-ray crystal structure of [Mn2{µ-C(CO)C6H4-Me-p}(CO)6(η-C5H5)]·0·5Et2O

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Carbon monoxide transfer to a metal co-ordinated carbyne ligand: X-ray crystal structure of [Mn2{µ-C(CO)C6H4-Me-p}(CO)6(η-C5H5)]·0·5Et2O

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