Homogeneously-catalyzed syntheses in supercritical fluids

作者: Philip G. Jessop

DOI: 10.1023/A:1019189600768

关键词:

摘要: Supercritical fluids (SCFs) differ from liquid solvents in a number of important properties, any which could potentially alter the performance chemical reaction performed supercritical medium. Although rate, yield and selectivity improvements as well environmental, health engineering benefits are all possible, little research has been reported on homogeneously-catalyzed syntheses SCFs. Several notable successes plus new techniques for solubilizing hydrophilic reagents SCFs encouraging further this growing field.

参考文章(88)
Viacheslav V Sychev, AA Vasserman, AD Kozlov, VA Zagoruchenko, GA Spiridonov, VA Tsymarny, None, Thermodynamic Properties of Ethane ,(1987)
Pablo G. Debenedetti, Supercritical Fluids: Fundamentals and Applications Developments in Food Engineering. pp. 30- 35 ,(1994) , 10.1007/978-1-4615-2674-2_6
Walter Leitner, Eckhard Dinjus, Franz Gaßner, Activation of carbon dioxide: IV. Rhodium-catalysed hydrogenation of carbon dioxide to formic acid☆ Journal of Organometallic Chemistry. ,vol. 475, pp. 257- 266 ,(1994) , 10.1016/0022-328X(94)84030-X
Anthony F. Lagalante, Brian N. Hansen, Thomas J. Bruno, Robert E. Sievers, Solubilities of Copper(II) and Chromium(III) .beta.-Diketonates in Supercritical Carbon Dioxide Inorganic Chemistry. ,vol. 34, pp. 5781- 5785 ,(1995) , 10.1021/IC00127A015
Jianliang Xiao, Sylvia C.A. Nefkens, Philip G. Jessop, Takao Ikariya, Ryoji Noyori, Asymmetric hydrogenation of α,β-unsaturated carboxylic acids in supercritical carbon dioxide Tetrahedron Letters. ,vol. 37, pp. 2813- 2816 ,(1996) , 10.1016/0040-4039(96)00436-4
Markku Rantakyl�, Olli Aaltonen, Enantioselective esterification of ibuprofen in supercritical carbon dioxide by immobilized lipase Biotechnology Letters. ,vol. 16, pp. 825- 830 ,(1994) , 10.1007/BF00133961
Thomas K. Sherwood, Robert E. Street, Robert C. Reid, The Properties of Gases and Liquids ,(1977)