Asymmetric syntheses based on 1,3-oxathianes. 2. Synthesis of chiral tertiary .alpha.-hydroxy aldehydes, .alpha.-hydroxy acids, glycols [R1R2C(OH)CH2OH], and carbinols [R1R2C(OH)Me] in high enantiomeric purity.

作者: Joseph E. Lynch , Ernest L. Eliel

DOI: 10.1021/JA00322A034

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摘要: Scission par le N-chlorosuccinimide de trimethyl-4,4,7 oxa-1thia-3 bicyclo [4.4.0] decanecarbinols, avec formation d'α-aldols. Etude l'oxydation et la reduction ces α-aldols

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