First experimental establishment of high internal pressure of molecular hydrogen developed in palladium during water electrolysis
作者： J.O.M. Bockris , Zoran S. Minevski
DOI: 10.1016/S0360-3199(97)00159-6
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摘要: Abstract The paper aims at examining the hypothesis of high internal pressure within voids in metals. method used was to form a void space inside cylindrical electrode coupled transducer. In about 1000 h 280 atm measured. It has been shown that slow diffusion hydrogen into prevents attainment practical time theoretical ∼10 atm.
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sci-hub.se 参考文章(6)
John Crank, The mathematics of diffusion ,(1956)
R.A. Oriani, P.H. Josephic, The effects of hydrogen on the room-temperature creep of spheroidized 1040-steel Acta Metallurgica. ,vol. 29, pp. 669- 674 ,(1981) , 10.1016/0001-6160(81)90149-8
V. Breger, E. Gileadi, Adsorption and absorption of hydrogen in palladium Electrochimica Acta. ,vol. 16, pp. 177- 190 ,(1971) , 10.1016/0013-4686(71)80001-4
J.O'M. Bockris, M.A. genshaw, M. Fullenwider, The electro-permeation of hydrogen into metals Electrochimica Acta. ,vol. 15, pp. 47- 60 ,(1970) , 10.1016/0013-4686(70)90006-X
R.A. Oriani, P.H. Josephic, Hydrogen-enhanced load relaxation in a deformed medium-carbon steel Acta Metallurgica. ,vol. 27, pp. 997- 1005 ,(1979) , 10.1016/0001-6160(79)90187-1
N. J. PETCH, P. STABLES, Delayed Fracture of Metals under Static Load Nature. ,vol. 169, pp. 842- 843 ,(1952) , 10.1038/169842A0