Introduction to Coal Photochemistry

作者: J. R. Darwent , A. F. Gaines

DOI: 10.1007/978-94-009-3045-2_10

关键词:

摘要: Invariably, coal extracts and solutions of liquids are not true at all but contain, besides simple molecules, a range much larger molecules even small particles. Consequently, despite their aromaticity, such materials do give ultraviolet absorption spectra, rather they scatter light. Information about the chemistry aromatic nuclei can be obtained, however, from fluorescence extracts, notably excitation spectra. Measurements commonly examine light emitted right angles to incident beam; problems scattering thereby overcome. Even suspensions 1 μm particles in water or chloroform emit spectra show mono, di polyaromatic structures present.

参考文章(13)
J. D. Coyle, J. A. Barltrop, Excited states in organic chemistry Wiley. ,(1975)
David Parker Craig, S. H. Walmsley, Excitons in molecular crystals : theory and applications W.A. Benjamin. ,(1968)
R. L. BROWN, Science in the Use of Coal Nature. ,vol. 182, pp. 24- 26 ,(1958) , 10.1038/182024A0
$^{13}$C n.m.r. Studies of Coal and Coal Extracts [and Discussion] Philosophical transactions - Royal Society. Mathematical, physical and engineering sciences. ,vol. 300, pp. 15- 41 ,(1981) , 10.1098/RSTA.1981.0045
E. R. Clark, J. R. Darwent, B. Demirci, K. Flunder, A. F. Gaines, A. C. Jones, Fluorescence of pyridine extracts of coals Energy & Fuels. ,vol. 1, pp. 392- 397 ,(1987) , 10.1021/EF00005A003
C.R. Landis, G.W. Sullivan, M.W. Pleil, W.L. Borst, J.C. Crelling, Pulsed laser fluorescence microscopy of coal macerals and dispersed organic material Fuel. ,vol. 66, pp. 984- 991 ,(1987) , 10.1016/0016-2361(87)90340-1
John A.G. Drake, Derry W. Jones, Brian S. Causey, Gordon F. Kirkbright, Shpol'skii luminescence spectroscopy of extracts of coal and coal-tar pitch Fuel. ,vol. 57, pp. 663- 666 ,(1978) , 10.1016/0016-2361(78)90017-0