High nitrogen-doped carbon/Mn3O4 hybrids synthesized from nitrogen-rich coordination polymer particles as supercapacitor electrodes

作者: Kuaibing Wang , Xiaobo Shi , Aiming Lu , Xiaoyan Ma , Zhiyang Zhang

DOI: 10.1039/C4DT02456G

关键词:

摘要: High nitrogen-doped carbon/Mn3O4 composites were synthesized by annealing nitrogen-rich Mn-based coordination polymer particles, and investigated electron microscopy, X-ray diffraction, electrochemical experiments. To assess the performance of high hybrids as electrode materials in supercapacitors, cyclic voltammetry galvanostatic charging–discharging measurements are performed. charged discharged faster have higher capacitance than nanostructures with low nitrogen amounts other reported ones. The is 94% retained after 1000 cycles at a constant current. These improvements can be attributed to carbon matrix, which promotes fast Faradaic charging discharging Mn3O4 motifs. could promising candidate material for high-capacity, low-cost, environmentally friendly supercapacitors.

参考文章(36)
X. Wang, X. Li, L. Zhang, Y. Yoon, P. K. Weber, H. Wang, J. Guo, H. Dai, N-doping of graphene through electrothermal reactions with ammonia. Science. ,vol. 324, pp. 768- 771 ,(2009) , 10.1126/SCIENCE.1170335
Zhenhai Wen, Xinchen Wang, Shun Mao, Zheng Bo, Haejune Kim, Shumao Cui, Ganhua Lu, Xinliang Feng, Junhong Chen, Crumpled Nitrogen‐Doped Graphene Nanosheets with Ultrahigh Pore Volume for High‐Performance Supercapacitor Advanced Materials. ,vol. 24, pp. 5610- 5616 ,(2012) , 10.1002/ADMA.201201920
Raghuram Chetty, Shankhamala Kundu, Wei Xia, Michael Bron, Wolfgang Schuhmann, Valentin Chirila, Waltraut Brandl, Thomas Reinecke, Martin Muhler, PtRu nanoparticles supported on nitrogen-doped multiwalled carbon nanotubes as catalyst for methanol electrooxidation Electrochimica Acta. ,vol. 54, pp. 4208- 4215 ,(2009) , 10.1016/J.ELECTACTA.2009.02.073
Yanchun Zhao, Sulian Nie, Huaiwen Wang, Jianniao Tian, Zhen Ning, Xiaoxiao Li, Direct synthesis of palladium nanoparticles on Mn3O4 modified multi-walled carbon nanotubes: A highly active catalyst for methanol electro-oxidation in alkaline media Journal of Power Sources. ,vol. 218, pp. 320- 330 ,(2012) , 10.1016/J.JPOWSOUR.2012.07.012
Hyung Mo Jeong, Jung Woo Lee, Weon Ho Shin, Yoon Jeong Choi, Hyun Joon Shin, Jeung Ku Kang, Jang Wook Choi, Nitrogen-doped graphene for high-performance ultracapacitors and the importance of nitrogen-doped sites at basal planes. Nano Letters. ,vol. 11, pp. 2472- 2477 ,(2011) , 10.1021/NL2009058
Jeong Woo Lee, Anthony S Hall, Jong-Duk Kim, Thomas E Mallouk, None, A Facile and Template-Free Hydrothermal Synthesis of Mn3O4 Nanorods on Graphene Sheets for Supercapacitor Electrodes with Long Cycle Stability Chemistry of Materials. ,vol. 24, pp. 1158- 1164 ,(2012) , 10.1021/CM203697W
Kim J Yaghi, OM, O'Keeffe, M, Ockwig NW, Chae, HK, Eddaoudi M, Reticular synthesis and the design of new materials Nature. ,vol. 423, pp. 705- 714 ,(2003) , 10.1038/NATURE01650
Dacheng Wei, Yunqi Liu, Yu Wang, Hongliang Zhang, Liping Huang, Gui Yu, Synthesis of N-Doped Graphene by Chemical Vapor Deposition and Its Electrical Properties Nano Letters. ,vol. 9, pp. 1752- 1758 ,(2009) , 10.1021/NL803279T
Guohai Xu, Xiaoguang Zhang, Peng Guo, Chengling Pan, Hongjie Zhang, Cheng Wang, MnII-based MIL-53 Analogues: Synthesis Using Neutral Bridging μ2-Ligands and Application in Liquid-Phase Adsorption and Separation of C6−C8 Aromatics Journal of the American Chemical Society. ,vol. 132, pp. 3656- 3657 ,(2010) , 10.1021/JA910818A