K2CO3-containing composite sorbents based on a ZrO2 aerogel for reversible CO2 capture from ambient air

作者: Janna V. Veselovskaya , Vladimir S. Derevschikov , Anton S. Shalygin , Dmitry A. Yatsenko

DOI: 10.1016/J.MICROMESO.2020.110624

关键词:

摘要: In this work, K 2 CO 3-containing composite materials were synthesized based on a mesoporous zirconia aerogel prepared by an epoxide-assisted sol-gel method using supercritical drying in ethanol. The porous ZrO 2 was impregnated with an aqueous solution of potassium carbonate to obtain composite materials with K 2 CO 3 weight content ranging from 9 to 29 wt%. All the composites were tested in the process of CO 2 absorption from the air with a relative humidity of 25% followed by thermal desorption at 200° C. The samples …

参考文章(44)
Sumit Bali, Miles A. Sakwa-Novak, Christopher W. Jones, Potassium incorporated alumina based CO2 capture sorbents: Comparison with supported amine sorbents under ultra-dilute capture conditions Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 486, pp. 78- 85 ,(2015) , 10.1016/J.COLSURFA.2015.09.020
Christopher N. Chervin, Brady J. Clapsaddle, Hsiang Wei Chiu, Alexander E. Gash, Joe H. Satcher,, Susan M. Kauzlarich, Aerogel Synthesis of Yttria-Stabilized Zirconia by a Non-Alkoxide Sol−Gel Route Chemistry of Materials. ,vol. 17, pp. 3345- 3351 ,(2005) , 10.1021/CM0503679
Janna V Veselovskaya, Vladimir S Derevschikov, Tatyana Yu Kardash, Aleksey G Okunev, None, Direct CO2 capture from ambient air by K2CO3/alumina composite sorbent for synthesis of renewable methane Renewable Bioresources. ,vol. 3, pp. 1- ,(2015) , 10.7243/2052-6237-3-1
Chuanwen Zhao, Xiaoping Chen, Edward J Anthony, Xi Jiang, Lunbo Duan, Ye Wu, Wei Dong, Changsui Zhao, None, Capturing CO2 in flue gas from fossil fuel-fired power plants using dry regenerable alkali metal-based sorbent Progress in Energy and Combustion Science. ,vol. 39, pp. 515- 534 ,(2013) , 10.1016/J.PECS.2013.05.001
J Mrowiec-Białoń, L Pająk, A.B Jarzębski, A.I Lachowski, J.J Malinowski, Preparation effects on zirconia aerogel morphology Journal of Non-crystalline Solids. ,vol. 225, pp. 115- 119 ,(1998) , 10.1016/S0022-3093(98)00016-7
Shinichi Hirano, Naoya Shigemoto, Shinichi Yamada, Hiromu Hayashi, Cyclic Fixed-Bed Operations over K2CO3-on-Carbon for the Recovery of Carbon Dioxide under Moist Conditions Bulletin of the Chemical Society of Japan. ,vol. 68, pp. 1030- 1035 ,(1995) , 10.1246/BCSJ.68.1030
Soo Chool Lee, Yong Mok Kwon, Suk Yong Jung, Joong Beom Lee, Chong Kul Ryu, Jae Chang Kim, Excellent thermal stability of potassium-based sorbent using ZrO2 for post combustion CO2 capture Fuel. ,vol. 115, pp. 97- 100 ,(2014) , 10.1016/J.FUEL.2013.07.007
Alexander F. Bedilo, Kenneth J. Klabunde, Synthesis of Catalytically Active Sulfated Zirconia Aerogels Journal of Catalysis. ,vol. 176, pp. 448- 458 ,(1998) , 10.1006/JCAT.1998.2052
Vladimir S. Derevschikov, Janna V. Veselovskaya, Tatyana Yu. Kardash, Dmitry A. Trubitsyn, Aleksey G. Okunev, Direct CO2 capture from ambient air using K2CO3/Y2O3 composite sorbent Fuel. ,vol. 127, pp. 212- 218 ,(2014) , 10.1016/J.FUEL.2013.09.060
Margarita Kantschewa, E. Vicente Albano, Gerhard Etrtl, Helmut Kno¨zinger, Infrared and x-ray photoelectron spectroscopy study of K2CO3/γ-Al2O3 Applied Catalysis. ,vol. 8, pp. 71- 84 ,(1983) , 10.1016/0166-9834(83)80054-2