Development of inorganic polymer by alkali-activation of untreated kaolinitic clay: Reaction stoichiometry, strength and dimensional stability

作者: Muayad Esaifan , Hubert Rahier , Ahmed Barhoum , Hani Khoury , Mohammed Hourani

DOI: 10.1016/J.CONBUILDMAT.2015.04.034

关键词:

摘要: Abstract An environmental friendly building material was developed by alkali-activation of untreated kaolinitic clay using sodium hydroxide. The reaction studied differential scanning calorimetry. chemical structure the produced inorganic polymer deduced from infrared spectroscopy, X-ray powder diffraction, thermogravimetric analysis, and electron microscopy to be tetrahydrate phase hydroxysodalite with a Na/Al ratio 4/3. Its strength stability were evaluated in terms compressive under dry saturated conditions different ratios mixing water NaOH. samples ranges between 45 50 MPa. wet after soaking show 20 25 MPa, alternating cycles drying wetting also 20–25 MPa.

参考文章(30)
S. Song, D. Sohn, H. M. Jennings, T. O. Mason, Hydration of alkali-activated ground granulated blast furnace slag Journal of Materials Science. ,vol. 35, pp. 249- 257 ,(2000) , 10.1023/A:1004742027117
Molecular Sieve Zeolites-II AMERICAN CHEMICAL SOCIETY. ,(1971) , 10.1021/BA-1971-0101
Werner Borchert, J�rgen Keidel, Beiträge zur Reaktionsfähigkeit der Silikate bei niedrigen Temperaturen Heidelberger Beitr�ge zur Mineralogie und Petrographie. ,vol. 1, pp. 17- 30 ,(1947) , 10.1007/BF01112366
H. Rahier, B. Van Mele, M. Biesemans, J. Wastiels, X. Wu, Low-temperature synthesized aluminosilicate glasses Journal of Materials Science. ,vol. 31, pp. 71- 79 ,(1996) , 10.1007/BF00355128
M. L. Granizo, M. T. Blanco, Alkaline Activation of Metakaolin An Isothermal Conduction Calorimetry Study Journal of Thermal Analysis and Calorimetry. ,vol. 52, pp. 957- 965 ,(1998) , 10.1023/A:1010176321136
A. Gualtieri, P. Norby, G. Artioli, J. Hanson, KINETICS OF FORMATION OF ZEOLITE NA-A LTA FROM NATURAL KAOLINITES pacific rim conference on multimedia. ,vol. 24, pp. 191- 199 ,(1997) , 10.1007/S002690050032
Benjamin C. McLellan, Ross P. Williams, Janine Lay, Arie van Riessen, Glen D. Corder, Costs and carbon emissions for geopolymer pastes in comparison to ordinary portland cement Journal of Cleaner Production. ,vol. 19, pp. 1080- 1090 ,(2011) , 10.1016/J.JCLEPRO.2011.02.010
Mahir Alkan, Çiğdem Hopa, Zürriye Yilmaz, Halil Güler, The effect of alkali concentration and solid/liquid ratio on the hydrothermal synthesis of zeolite NaA from natural kaolinite Microporous and Mesoporous Materials. ,vol. 86, pp. 176- 184 ,(2005) , 10.1016/J.MICROMESO.2005.07.008
Darko Krizan, Branislav Zivanovic, Effects of dosage and modulus of water glass on early hydration of alkali–slag cements Cement and Concrete Research. ,vol. 32, pp. 1181- 1188 ,(2002) , 10.1016/S0008-8846(01)00717-7