Gas Storage in Fullerenes

作者: G. E. Gadd , P. J. Evans , S. Kennedy , M. James , M. Elcombe

DOI: 10.1080/10641229909350304

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摘要: Abstract Fullerenes and in particular C60 have been shown to store effectively a wide range of gases from simple monatomic rare diatomics polyatomics. A review the research this area conducted at ANSTO is given. The trapping Ar, Kr, Xe, CO2 are discussed detail whilst preliminary results pertaining N2O, CH4, CF4, C2H6 SF6 also reported. techniques used elucidate both structure new fullerene intercalated solid trapped gas itself. preponderant used, include infra-red absorption spectroscopy (IR), X-ray powder diffraction (XRD), neutron (NRD), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA).

参考文章(54)
Eric Whittle, David A. Dows, George C. Pimentel, Matrix Isolation Method for the Experimental Study of Unstable Species Journal of Chemical Physics. ,vol. 22, pp. 1943- 1943 ,(1954) , 10.1063/1.1739957
I. Holleman, Dynamics of CO in solid C60 [S.l. : s.n.]. ,(1998)
Linus Pauling, The Nature of the Chemical Bond ,(1939)
Roger A. Assink, James E. Schirber, Douglas A. Loy, Bruno Morosin, Gary A. Carlson, Intercalation of molecular species into the interstitial sites of fullerene Journal of Materials Research. ,vol. 7, pp. 2136- 2143 ,(1992) , 10.1557/JMR.1992.2136
A. R. Kortan, N. Kopylov, S. Glarum, E. M. Gyorgy, A. P. Ramirez, R. M. Fleming, F. A. Thiel, R. C. Haddon, Superconductivity at 8.4 K in calcium-doped C60 Nature. ,vol. 355, pp. 529- 532 ,(1992) , 10.1038/355529A0
J. E. Schirber, G. H. Kwei, J. D. Jorgensen, R. L. Hitterman, B. Morosin, Room-temperature compressibility of C60: Intercalation effects with He, Ne, and Ar. Physical Review B. ,vol. 51, pp. 12014- 12017 ,(1995) , 10.1103/PHYSREVB.51.12014
B. Morosin, J. D. Jorgensen, Simine Short, G. H. Kwei, J. E. Schirber, Ne-intercalated C60: Pressure dependence of Ne-site occupancies. Physical Review B. ,vol. 53, pp. 1675- 1678 ,(1996) , 10.1103/PHYSREVB.53.1675
G.E Gadd, M James, S Moricca, D Cassidy, P.J Evans, B Collins, R.S Armstrong, Polyatomic gas storage in fullerenes-CO2 forced into the C60 lattice Journal of Physics and Chemistry of Solids. ,vol. 59, pp. 1383- 1391 ,(1998) , 10.1016/S0022-3697(98)00255-8