The Chemistry of the Dealumination of Faujasite Zeolites with Silicon Tetrachloride

作者: Johan A. Martens , Piet J. Grobet , Peter A. Jacobs

DOI: 10.1016/S0167-2991(08)64600-5

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摘要: Abstract Literature data on the dealumination with SiCl4 of X and Y type zeolites Na, Li, H, Ca or La as charge compensating cations is reviewed. The properties final zeolite products, in particular degree dealumination, crystallinity, mesoporosity, nature content extra-framework aluminium silicon species are explained based chemistry involved different steps procedures. reactivity towards framework atoms location associated over accessible hidden sites.

参考文章(42)
Jule A. Rabo, Zeolite chemistry and catalysis American Chemical Society. ,(1976)
Dieter Michel, Günter Engelhardt, High-resolution solid-state NMR of silicates and zeolites John Wiley and Sons,New York, NY. ,(1987)
Hermann K. Beyer, Ita M. Belenykaja, Ferenc Hange, Mia Tielen, Piet J. Grobet, Peter A. Jacobs, Preparation of high-silica faujasites by treatment with silicon tetrachloride Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 81, pp. 2889- 2901 ,(1985) , 10.1039/F19858102889
W MORTIER, Zeolite electronegativity related to physicochemical properties Journal of Catalysis. ,vol. 55, pp. 138- 145 ,(1978) , 10.1016/0021-9517(78)90200-2
Jean-Pierre Gilson, Grant C. Edwards, Alan W. Peters, Koppuswamy Rajagopalan, Richard F. Wormsbecher, Terry G. Roberie, Michael P. Shatlock, Penta-co-ordinated aluminium in zeolites and aluminosilicates Journal of The Chemical Society, Chemical Communications. pp. 91- 92 ,(1987) , 10.1039/C39870000091
Günter Engelhardt, Endel Lippmaa, Märt Mägi, Ordering of silicon and aluminium ions in the framework of NaX zeolites. A solid-state high-resolution29Si n.m.r. study J. Chem. Soc., Chem. Commun.. ,vol. 0, pp. 712- 713 ,(1981) , 10.1039/C39810000712
G. Engelhardt, U. Lohse, E. Lippmaa, M. Tarmak, M. M�gi, 29Si‐NMR‐Untersuchungen zur Verteilung der Silicium‐und Aluminiumatome im Alumosilicatgitter von Zeolithen mit Faujasit‐Struktur Zeitschrift für anorganische und allgemeine Chemie. ,vol. 482, pp. 49- 64 ,(1981) , 10.1002/ZAAC.19814821106