ESR Studies of Cu, Ag, and Au Atoms Isolated in Rare‐Gas Matrices

作者: Paul H. Kasai , D. McLeod

DOI: 10.1063/1.1676280

关键词:

摘要: Electron spin resonance spectra were observed on Cu, Ag, and Au atoms isolated in Ne, Ar, Kr, Xe matrices at ∼ 4°K. The hyperfine coupling constants the g values determined examined for matrix effect. With xenon a superhyperfine structure with magnetic nuclei was partially resolved, by means of computer simulation, it shown that these are substitutionally incorporated within lattice. Also an evidence atom‐vacancy pairing Cu Ne matrix.

参考文章(10)
Peter B. Ayscough, Electron Spin Resonance in Chemistry ,(1967)
Paul H. Kasai, William Weltner, Earl B. Whipple, Orientation of NO2 and Other Molecules in Neon Matrices at 4°K The Journal of Chemical Physics. ,vol. 42, pp. 1120- 1121 ,(1965) , 10.1063/1.1696051
F. J. Adrian, Matrix Effects on the Electron Spin Resonance Spectra of Trapped Hydrogen Atoms Journal of Chemical Physics. ,vol. 32, pp. 972- 981 ,(1960) , 10.1063/1.1730906
Günter Wessel, Hin Lew, Hyperfine Structures of Silver and Gold by the Atomic Beam Magnetic Resonance Method Physical Review. ,vol. 92, pp. 641- 646 ,(1953) , 10.1103/PHYSREV.92.641
Frank Herman, Sherwood Skillman, John Arents, Atomic Structure Calculations Journal of The Electrochemical Society. ,vol. 111, pp. 87C- ,(1964) , 10.1149/1.2426131
C. K. Ien, V. A. Bowers, E. L. Cochran, S. N. Foner, Electron Spin Resonance of Alkali Atoms in Inert-Gas Matrices Physical Review. ,vol. 126, pp. 1749- 1757 ,(1962) , 10.1103/PHYSREV.126.1749
Paul H. Kasai, Earl B. Whipple, William Weltner, ESR of Cu(NO3)2 and CuF2 Molecules Oriented in Neon and Argon Matrices at 4°K Journal of Chemical Physics. ,vol. 44, pp. 2581- 2591 ,(1966) , 10.1063/1.1727096
L. Brewer, B. A. King, J. L. Wang, B. Meyer, G. F. Moore, Absorption Spectrum of Silver Atoms in Solid Argon, Krypton, and Xenon The Journal of Chemical Physics. ,vol. 49, pp. 5209- 5213 ,(1968) , 10.1063/1.1670036
S. N. Foner, E. L. Cochran, V. A. Bowers, C. K. Jen, Multiple Trapping Sites for Hydrogen Atoms in Rare Gas Matrices Journal of Chemical Physics. ,vol. 32, pp. 963- 971 ,(1960) , 10.1063/1.1730905
Y. Ting, H. Lew, Hyperfine Structure ofCu63andCu65 Physical Review. ,vol. 105, pp. 581- 588 ,(1957) , 10.1103/PHYSREV.105.581