Novel Iminocoumarin Derivatives: Synthesis, Spectroscopic and Computational Studies

作者: Santosh B. Chemate , Nagaiyan Sekar

DOI: 10.1007/S10895-015-1648-4

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摘要: Three novel iminocoumarin derivatives with high quantum yield are synthesized from 3-benzimidazole substituted coumarin and different aromatic aldehydes. The photophysical behavior of the compounds was studied using UV-visible fluorescence spectroscopy in polar non-polar solvents. show absorption maxima at around 450 nm emission 500 nm. yields dichloromethane chloroform more than 0.90. absorption, dependent on polarity Along an intense these shoulder peak solvent plots revealed charge transfer process molecules donor to acceptor. Density Functional Theory Time Dependent computations have been used understanding structural, molecular, electronic parameters dyes. dyes were characterized by FT-IR, 1H NMR, 13C NMR mass spectral analysis.

参考文章(50)
Bernard Valeur, Mário Nuno Berberan-Santos, Molecular fluorescence : principles and applications Wiley-VCH. ,(2012) , 10.1002/9783527650002
Mehdi Fakhfakh, Hamida Turki, Souhir Abid, Rachid El Gharbi, Suzanne Fery-Forgues, Preparation and optical properties of new fluorescent iminocoumarins: Study of N-acyl-derivatives Journal of Photochemistry and Photobiology A-chemistry. ,vol. 185, pp. 13- 18 ,(2007) , 10.1016/J.JPHOTOCHEM.2006.04.036
Hamida Turki, Souhir Abid, Suzanne Fery-Forgues, Rachid El Gharbi, Optical properties of new fluorescent iminocoumarins: Part 1 Dyes and Pigments. ,vol. 73, pp. 311- 316 ,(2007) , 10.1016/J.DYEPIG.2006.01.001
Heiner Detert, Volker Schmitt, Acidochromism of stilbenoid chromophores with a p‐aminoaniline centre Journal of Physical Organic Chemistry. ,vol. 19, pp. 603- 607 ,(2006) , 10.1002/POC.1091
L. Bilot, A. Kawski, Zur Theorie des Einflusses von Lösungsmitteln auf die Elektronenspektren der Moleküle Zeitschrift für Naturforschung A. ,vol. 17, pp. 621- 627 ,(1962) , 10.1515/ZNA-1962-0713
S. Dhami, A. J. De Mello, G. Rumbles, S. M. Bishop, D. Phillips, A. Beeby, PHTHALOCYANINE FLUORESCENCE AT HIGH CONCENTRATION: DIMERS OR REABSORPTION EFFECT? Photochemistry and Photobiology. ,vol. 61, pp. 341- 346 ,(1995) , 10.1111/J.1751-1097.1995.TB08619.X
Axel D. Becke, A New Mixing of Hartree-Fock and Local Density-Functional Theories Journal of Chemical Physics. ,vol. 98, pp. 1372- 1377 ,(1993) , 10.1063/1.464304
Giuseppe Micali, Paola Currò, Giuseppe Calabrò, High-performance liquid chromatographic separation and determination of fluorescent whitening agents in detergents The Analyst. ,vol. 109, pp. 155- 158 ,(1984) , 10.1039/AN9840900155
Guilford Jones, Mohammad A. Rahman, Fluorescence Properties of Coumarin Laser Dyes in Aqueous Polymer Media. Chromophore Isolation in Poly(methacrylic acid) Hypercoils The Journal of Physical Chemistry. ,vol. 98, pp. 13028- 13037 ,(1994) , 10.1021/J100100A035
P. Wlodarczyk, S. Komarneni, R. Roy, W. B. White, Enhanced fluorescence of coumarin laser dye in the restricted geometry of a porous nanocomposite Journal of Materials Chemistry. ,vol. 6, pp. 1967- 1969 ,(1996) , 10.1039/JM9960601967