A tetrapyridine ligand with a rigid tetrahedral core forms metal–organic frameworks with PtS type architecture

作者: Christopher B. Caputo , V. Nicholas Vukotic , Natalie M. Sirizzotti , Stephen J. Loeb

DOI: 10.1039/C1CC12188J

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摘要: A new tetradentate, pyridine ligand with a rigid tetrahedral core can be prepared in good yield by cross-coupling methodology. Two metal organic framework structures of Cu(II) PtS-type topology having carbon atom as the node have been characterized utilising this ligand.

参考文章(24)
Kouzou Matsumoto, Masaki Kannami, Daisuke Inokuchi, Hiroyuki Kurata, Takeshi Kawase, Masaji Oda, Tetrakis(4-pyridyl)methane: Synthesis, Properties, and a Diamondoid Network Structure of Its Silver(I) Complex Organic Letters. ,vol. 9, pp. 2903- 2906 ,(2007) , 10.1021/OL071189N
Abdul Malik Puthan Peedikakkal, Charlene Shi Yun Peh, Lip Lin Koh, Jagadese J. Vittal, Metal-organic frameworks containing a tetrapyridylcyclobutane ligand derived from isomerization reaction. Inorganic Chemistry. ,vol. 49, pp. 6775- 6777 ,(2010) , 10.1021/IC100853H
Christian Kaes, Alexander Katz, Mir Wais Hosseini, Bipyridine:  The Most Widely Used Ligand. A Review of Molecules Comprising at Least Two 2,2‘-Bipyridine Units Chemical Reviews. ,vol. 100, pp. 3553- 3590 ,(2000) , 10.1021/CR990376Z
Dennis J. Hoffart, Nicolle C. Habermehl, Stephen J. Loeb, 4,4'-Bipyridine-N-monoxide. A hybrid ligand for building networks using a combination of metal-ligand and hydrogen-bonding interactions. Dalton Transactions. pp. 2870- 2875 ,(2007) , 10.1039/B703456C
Patrick E. Ryan, Christophe Lescop, Dominic Laliberté, Tamara Hamilton, Thierry Maris, James D. Wuest, Engineering new metal-organic frameworks built from flexible tetrapyridines coordinated to Cu(II) and Cu(I). Inorganic Chemistry. ,vol. 48, pp. 2793- 2807 ,(2009) , 10.1021/IC8019809
Jin-Song Hu, Yong-Jia Shang, Xiao-qiang Yao, Ling Qin, Yi-Zhi Li, Zi-Jian Guo, He-Gen Zheng, Zi-Ling Xue, Syntheses, Structures, and Photoluminescence of Five New Metal−Organic Frameworks Based on Flexible Tetrapyridines and Aromatic Polycarboxylate Acids Crystal Growth & Design. ,vol. 10, pp. 2676- 2684 ,(2010) , 10.1021/CG1001557
Susumu Kitagawa, Ryo Kitaura, Shin-ichiro Noro, Functional Porous Coordination Polymers Angewandte Chemie International Edition. ,vol. 43, pp. 2334- 2375 ,(2004) , 10.1002/ANIE.200300610
L Thompson, Polynuclear coordination complexes—from dinuclear to nonanuclear and beyond Coordination Chemistry Reviews. ,vol. 233, pp. 193- 206 ,(2002) , 10.1016/S0010-8545(02)00101-7
Jaheon Kim, Banglin Chen, Theresa M. Reineke, Hailian Li, Mohamed Eddaoudi, David B. Moler, Michael O'Keeffe, Omar M. Yaghi, Assembly of metal-organic frameworks from large organic and inorganic secondary building units: new examples and simplifying principles for complex structures. Journal of the American Chemical Society. ,vol. 123, pp. 8239- 8247 ,(2001) , 10.1021/JA010825O
Kouzou Matsumoto, Daisuke Inokuchi, Yasukazu Hirao, Hiroyuki Kurata, Takashi Kubo, Hydrogen-Bonded Quartz-type Network of Diprotonated Tetrakis(4-pyridyl)methane Dications Crystal Growth & Design. ,vol. 10, pp. 2854- 2856 ,(2010) , 10.1021/CG1003353