A comparative examination of the adsorption mechanism of an anionic textile dye (RBY 3GL) onto the powdered activated carbon (PAC) using various the isotherm models and kinetics equations with linear and non-linear methods

作者: Metin Açıkyıldız , Ahmet Gürses , Kübra Güneş , Duygu Yalvaç

DOI: 10.1016/J.APSUSC.2015.07.021

关键词:

摘要: Abstract The present study was designed to compare the linear and non-linear methods used check compliance of experimental data corresponding isotherm models (Langmuir, Freundlich, Redlich–Peterson) kinetics equations (pseudo-first order pseudo-second order). In this context, adsorption experiments were carried out remove an anionic dye, Remazol Brillant Yellow 3GL (RBY), from its aqueous solutions using a commercial activated carbon as sorbent. effects contact time, initial RBY concentration, temperature onto adsorbed amount investigated. dye increased with time equilibrium attained after 240 min. enhanced temperature, suggesting that process is endothermic. analyzed Langmuir, Redlich–Peterson in predict isotherm. It determined fitted Langmuir isotherms. also found follow pseudo second-order kinetic model. According data, it determination coefficients obtained method higher than those method.

参考文章(37)
Fuat Güzel, İlhan Uzun, Determination of the Micropore Structures of Activated Carbons by Adsorption of Various Dyestuffs from Aqueous Solution Turkish Journal of Chemistry. ,vol. 26, pp. 369- 378 ,(2002)
Zheng Gu, Manglai Gao, Zhongxin Luo, Laifu Lu, Yage Ye, Yuening Liu, Bis-pyridinium dibromides modified organo-bentonite for the removal of aniline from wastewater: A positive role of π–π polar interaction Applied Surface Science. ,vol. 290, pp. 107- 115 ,(2014) , 10.1016/J.APSUSC.2013.11.008
E. Zuriaga-Agustí, E. Alventosa-deLara, S. Barredo-Damas, M.I. Alcaina-Miranda, M.I. Iborra-Clar, J.A. Mendoza-Roca, Performance of ceramic ultrafiltration membranes and fouling behavior of a dye-polysaccharide binary system. Water Research. ,vol. 54, pp. 199- 210 ,(2014) , 10.1016/J.WATRES.2014.01.064
Semra Karaca, Ahmet Gürses, M Açıkyıldız, M Ejder, None, Adsorption of cationic dye from aqueous solutions by activated carbon Microporous and Mesoporous Materials. ,vol. 115, pp. 376- 382 ,(2008) , 10.1016/J.MICROMESO.2008.02.008
Z Al-Qodah, Adsorption of dyes using shale oil ash Water Research. ,vol. 34, pp. 4295- 4303 ,(2000) , 10.1016/S0043-1354(00)00196-2
K.Y. Foo, B.H. Hameed, Insights into the modeling of adsorption isotherm systems Chemical Engineering Journal. ,vol. 156, pp. 2- 10 ,(2010) , 10.1016/J.CEJ.2009.09.013
G. McKay, H. S. Blair, J. Gardner, The adsorption of dyes in chitin. III. Intraparticle diffusion processes Journal of Applied Polymer Science. ,vol. 28, pp. 1767- 1778 ,(1983) , 10.1002/APP.1983.070280519
Ahmet Gürses, Semra Karaca, Fatma Aksakal, Metin Açikyildiz, Monomer and micellar adsorptions of CTAB onto the clay/water interface Desalination. ,vol. 264, pp. 165- 172 ,(2010) , 10.1016/J.DESAL.2010.07.022