Arene ligand exchange in arene cyclopentadienyliron complexes
作者： A.N. Nesmeyanov , N.A. Vol'kenau , L.S. Shilovtseva , V.A. Petrakova
DOI: 10.1016/S0022-328X(00)86562-6
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摘要: Abstract It has been found that electroneutral arenecyclopentadienyl π-complexes of iron, AreneFeC 5 H (Arene = C 6 , 10 8 ), in the presence donor solvents exchange their arene ligands for π-cyclopentadienyl ligand, other arenes, CO or P(OPh) 3 . These reactions lead according to ferrocene, some new arenecyclopentadienyliron and dimers type [C FeL 2 ] where L CO,
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