Fluid mixtures in the CHO system at high pressure and temperature

摘要: Interaction energy parameters (Wij) for polar-polar and polar-nonpolar mixtures of gases (H2, O2, CO2, H2O, CO CH4) have been calculated using the Kihara Stockmayer potentials, respectively. Using mixing rules averaging dimensional properties geometric mean potential parameters, Wij data are binary mixtures. The interaction used with van Laar solution model found to reproduce experimental well. has tested against phase equilibrium on solid-fluid reactions. Examples some applications in systems Mg-Si-O-H, Fe-O C-H-O presented.