Synthesis, characterization and molecular structure of [1-HOCPh2-2-NHMe2C6H4][MeSO3] · MeSO3H
作者： Harbi Tomah Al-Masri , Joachim Sieler , Evamarie Hey-Hawkins
DOI: 10.1016/J.POLY.2005.06.002
关键词:
摘要: Abstract BEt2(OSO2CH3) was treated with 1-HOCPh2-2-NMe2C6H4 (1) in the presence of acetic acid to give a red oily residue, which separated by column chromatography into two products [1-HOCPh2-2-NHMe2C6H4][MeSO3] · MeSO3H (2) and known compound (BEt)2(μ-O)(μ-O,O′-O2CCH3)2 (3). Compound 2 prepared independently from 1 methylsulfonic acid. characterized spectroscopically (NMR, IR) crystal structure determination. The latter shows association ions one molecule [1-HOCPh2-2-NHMe2C6H4]+, [MeSO3]− MeSO3H hydrogen bonding.
elsevier.com
sci-hub.se 参考文章(14)
Robert Schlengermann, Joachim Sieler, Evamarie Hey-Hawkins, Synthesis and Molecular Structures of the Base-stabilized Arylboron Dichlorides BCl2{2,6-(NEt2CH2)2C6H3} and BCl2{2-(NMe2CH2)C6H4} Main Group Chemistry. ,vol. 2, pp. 141- 148 ,(1997) , 10.1080/10241229712331341274
J. Clare Speakman, Acid salts of carboxylic acids, crystals with some ‘very short” hydrogen bonds Structure and Bonding. pp. 141- 199 ,(1972) , 10.1007/BFB0117543
Harbi Tomah Al-Masri, Joachim Sieler, Peter Lönnecke, Steffen Blaurock, Konstantin Domasevitch, Evamarie Hey-Hawkins, Synthesis and molecular structures of (2-dialkylaminophenyl)alcohols and of 2-phenylaminoalkyl-dimethylaminobenzene derivatives Tetrahedron. ,vol. 60, pp. 333- 339 ,(2004) , 10.1016/J.TET.2003.11.022
Harbi T. Al-Masri, Joachim Sieler, Peter Lönnecke, Peter C. Junk, Evamarie Hey-Hawkins, Synthesis, Characterization, and Crystal Structures of Novel Intramolecularly Base-Stabilized Borane Derivatives with Six- and Seven-Membered Chelate Rings Inorganic Chemistry. ,vol. 43, pp. 7162- 7169 ,(2004) , 10.1021/IC049352N
Harbi T. Al-Masri, Joachim Sieler, Peter C. Junk, Konstantin V. Domasevitch, Evamarie Hey-Hawkins, Synthesis and characterization of novel intramolecularly base-stabilized BEt2 and BEt derivatives: molecular structures of 1-Et2BOCPh2-2-NMe2C6H4, 1-(CH3COO)EtBOCCy2-2-NMe2C6H4 and BEt(1-OCPh2CH2-2-NMe2C6H4)2 Journal of Organometallic Chemistry. ,vol. 690, pp. 469- 476 ,(2005) , 10.1016/J.JORGANCHEM.2004.09.071
Robert Schlengermann, Joachim Sieler, Svea Jelonek, Evamarie Hey-Hawkins, Different donor binding modes of the pincer ligand2,6-bis[(diethylamino)-methyl]phenyl: intermolecularly chelating inLi[2,6-(NEt2CH2)2C6H3] and both mono- and bi-dentate inBCl2{2-[BCl3(NEt2CH2)]-6-(NEt2CH2)C6H3} Chemical Communications. pp. 197- 198 ,(1997) , 10.1039/A606670D
Yasunori Tsuzuki, Katsumi Chiba, Kazuhiro Mizuno, Kyoji Tomita, Kenji Suzuki, Practical synthesis of (3S,4S)-3-methoxy-4-methylaminopyrrolidine Tetrahedron: Asymmetry. ,vol. 12, pp. 2989- 2997 ,(2001) , 10.1016/S0957-4166(01)00530-4
Ingeborg Kronawitter, Heinrich Nöth, Beiträge zur Chemie des Bors, LIX. Notiz zur Darstellung des Tris(tert.-butyloxy)-borans und anderer tert.-Butyloxyborane Chemische Berichte. ,vol. 105, pp. 2423- 2426 ,(1972) , 10.1002/CBER.19721050736
Harbi Tomah Al-Masri, Joachim Sieler, Steffen Blaurock, Peter L�nnecke, Peter C. Junk, Evamarie Hey-Hawkins, Synthesis and Characterization of Novel Intramolecularly Base‐stabilized Boron Halides. Molecular Structures of 1‐X2BOCR1R2‐2‐NMe2C6H4 [R1 = R2 = Ph, X = Cl or F; R1 = R2 = Cy, X = Cl] and [1‐LiN(Ph)C(H)Ph‐2‐NMe2C6H4]2 Zeitschrift für anorganische und allgemeine Chemie. ,vol. 631, pp. 518- 523 ,(2005) , 10.1002/ZAAC.200400375
Swiatoslav Trofimenko, Boryl sulfonates, a new class of borylating agents Journal of the American Chemical Society. ,vol. 91, pp. 2139- 2140 ,(1969) , 10.1021/JA01036A064