Effects of Sodium Carbonate Additive on the Hydroliquefaction of a Sub-bituminous Coal with Fe-Based Catalyst under Mild Conditions

作者: Sheng Huang , Shiyong Wu , Youqing Wu , Jinsheng Gao

DOI: 10.1021/ACS.ENERGYFUELS.7B02560

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摘要: In this paper, the influence of Na2CO3 (NC) on hydroliquefaction performances Hongliulin (HLL) coal with an Fe-based catalyst, γ-FeOOH (FC), under mild conditions was investigated, and properties resulting preasphaltene asphaltene were examined. Results show that addition NC to FC-catalyzed liquefaction significantly promoted conversion oil production reduced water conditions, especially at high initial H2 pressure. The consumption (0.53–1.93%) is much smaller than traditional processes, FC can enhance consumption, runs weak hydrogen donor solvents. order important factor which affect activity binary catalysts. There exists a prominent synergistic effect between in HLL hydroliquefaction, could be ascribed combined promotion actions for ...

参考文章(41)
Isao Mochida, Kinya Sakanishi, Nobuo Suzuki, Masaaki Sakurai, Yutaka Tsukui, Takao Kaneko, Progresses of coal liquefaction catalysts in Japan Catalysis Surveys From Japan. ,vol. 2, pp. 17- 30 ,(1998) , 10.1023/A:1019049618725
Yuan C. Fu, Eugene G. Illig, Sol J. Metlin, Conversion of manure to oil by catalytic hydrotreating Environmental Science & Technology. ,vol. 8, pp. 737- 740 ,(1974) , 10.1021/ES60093A013
Liang Li, Sheng Huang, Shi-Yong Wu, You-Qing Wu, Jin-Sheng Gao, Roles of Na2CO3 in lignite hydroliquefaction with Fe-based catalyst Fuel Processing Technology. ,vol. 138, pp. 109- 115 ,(2015) , 10.1016/J.FUPROC.2015.05.018
Peter J. Cassidy, W.Roy Jackson, Frank P. Larkins, Richard Sakurovs, Hydrogenation of brown coal Fuel. ,vol. 65, pp. 1057- 1061 ,(1986) , 10.1016/0016-2361(86)90167-5
Jingchong Yan, Zonqing Bai, Wen Li, Jin Bai, Direct liquefaction of a Chinese brown coal and CO2 gasification of the residues Fuel. ,vol. 136, pp. 280- 286 ,(2014) , 10.1016/J.FUEL.2014.07.054
Na-oki Ikenaga, Chiyo Ueda, Takao Matsui, Munetaka Ohtsuki, Toshimitsu Suzuki, Co-liquefaction of Micro Algae with Coal Using Coal Liquefaction Catalysts Energy & Fuels. ,vol. 15, pp. 350- 355 ,(2001) , 10.1021/EF000129U
Hengfu Shui, Zhenyi Cai, Chunbao Xu, Recent Advances in Direct Coal Liquefaction Energies. ,vol. 3, pp. 155- 170 ,(2010) , 10.3390/EN3020155
Hee-Jun Eom, Dae-Won Lee, Yoon-Ki Hong, Sang-Ho Chung, Myung-gi Seo, Kwan-Young Lee, Effects of a sodium carbonate (Na2CO3) additive on the conversion of phenethyl phenyl ether (PPE) in high-temperature water Applied Catalysis A: General. ,vol. 472, pp. 152- 159 ,(2014) , 10.1016/J.APCATA.2013.12.007
Peter J. Cassidy, W.Roy Jackson, Frank P. Larkins, Michael B. Louey, Richard J. Sakurovs, Promoters for the liquefaction of wet Victorian brown coal in carbon monoxide Fuel Processing Technology. ,vol. 14, pp. 231- 246 ,(1986) , 10.1016/0378-3820(86)90025-1
Paul Painter, Ruveyda Cetiner, Nuerxida Pulati, Maria Sobkowiak, Jonathan Mathews, Dispersion of Liquefaction Catalysts in Coal Using Ionic Liquids Energy & Fuels. ,vol. 24, pp. 3086- 3092 ,(2010) , 10.1021/EF100158V