Polyaniline-intercalated graphene oxide sheet and its transition to a nanotube through a self-curling process
作者： Y.F. Huang , C.W. Lin
DOI: 10.1016/J.POLYMER.2012.01.025
关键词:
摘要: Abstract This study reports the preparation of graphene oxide (GO)/polyaniline (PANI) nanotubes through polymerizing aniline monomers in presence GO sheets. Transmission electron microscopy (TEM) reveals that obtained GO/PANI have an outer diameter ∼120 nm and inner 15 nm. Fourier transform infrared (FT-IR) spectra thermogravimetric analysis (TGA) curves verify coexistence PANI produced nanotubes. X-ray diffraction patterns identify intercalation chains between Specifically, SEM images reveal formation polyaniline-intercalated sheets earlier stage. Subsequently, these initially-formed would into a self-curling process. The changes molecular structures doping states polyaniline molecules during polymerization process are thought to be responsible for behavior. Compared with pristine nanotubes, exhibit even higher electrical conductivity manifest their great potential applications various electrochemical devices.
elsevier.com
sci-hub.se 参考文章(40)
Wei Li, Meifang Zhu, Qinghua Zhang, Dajun Chen, Expanded conformation of macromolecular chain in polyaniline with one-dimensional nanostructure prepared by interfacial polymerization Applied Physics Letters. ,vol. 89, pp. 103110- ,(2006) , 10.1063/1.2345376
Nailiang Yang, Jin Zhai, Meixiang Wan, Dan Wang, Lei Jiang, Layered nanostructures of polyaniline with graphene oxide as the dopant and template Synthetic Metals. ,vol. 160, pp. 1617- 1622 ,(2010) , 10.1016/J.SYNTHMET.2010.05.029
Yan Gao, Hin-Lap Yip, Kung-Shih Chen, Kevin M. O’Malley, Orb Acton, Ying Sun, Guy Ting, Hongzheng Chen, Alex K.-Y. Jen, Surface Doping of Conjugated Polymers by Graphene Oxide and Its Application for Organic Electronic Devices Advanced Materials. ,vol. 23, pp. 1903- 1908 ,(2011) , 10.1002/ADMA.201100065
F.A. Viva, E.M. Andrade, F.V. Molina, M.I. Florit, Electropolymerization of 2-methoxy aniline. Electrochemical and spectroscopical product characterization Journal of Electroanalytical Chemistry. ,vol. 471, pp. 180- 189 ,(1999) , 10.1016/S0022-0728(99)00281-8
Trevor J. Dines, Louise D. MacGregor, Colin H. Rochester, The surface acidity of oxides probed by IR spectroscopy of adsorbed diazines Physical Chemistry Chemical Physics. ,vol. 3, pp. 2676- 2685 ,(2001) , 10.1039/B102047L
Zhiming Zhang, Zhixiang Wei, Meixiang Wan, Nanostructures of polyaniline doped with inorganic acids Macromolecules. ,vol. 35, pp. 5937- 5942 ,(2002) , 10.1021/MA020199V
Guo-Dong Fu, Guo Liang Li, K.G. Neoh, E.T. Kang, Hollow polymeric nanostructures—Synthesis, morphology and function Progress in Polymer Science. ,vol. 36, pp. 127- 167 ,(2011) , 10.1016/J.PROGPOLYMSCI.2010.07.011
L. Abell, S.J. Pomfret, P.N. Adams, A.P. Monkman, Thermal studies of doped polyaniline Synthetic Metals. ,vol. 84, pp. 127- 128 ,(1997) , 10.1016/S0379-6779(97)80678-9
Z. Wang, S. Zhou, L. Wu, Preparation of Rectangular WO3·H2O Nanotubes Under Mild Conditions Advanced Functional Materials. ,vol. 17, pp. 1790- 1794 ,(2007) , 10.1002/ADFM.200601195
Thierry Cassagneau, Janos H. Fendler, High Density Rechargeable Lithium‐Ion Batteries Self‐Assembled from Graphite Oxide Nanoplatelets and Polyelectrolytes Advanced Materials. ,vol. 10, pp. 877- 881 ,(1998) , 10.1002/(SICI)1521-4095(199808)10:11<877::AID-ADMA877>3.0.CO;2-1