Orthorhombic A1C60: A conducting linear alkali fulleride polymer?

作者: S. Pekker , L. Forró , L. Mihály , A. Jánossy

DOI: 10.1016/0038-1098(94)90796-X

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摘要: Abstract We suggest that the orthorhombic phases of alkali fullerides, o-A 1 C 60 (A=K, Rb, Cs), are linear polyners formed in solid state at about 400 K by a [2+2] cycloaddition reaction between fulleride ions fcc high temperature phase. The electronic structure polymers is quasi-one-dimensional.

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