Pore connectivity and tracer migration of typical shales in south China

作者: Mengdi Sun , Bingsong Yu , Qinhong Hu , Rui Yang , Yifan Zhang

DOI: 10.1016/J.FUEL.2017.04.086

关键词:

摘要: Abstract Pore connectivity of shale is a critical factor in gas migration and production. In order to investigate the pore from three typical formations south China (Longmaxi, Niutitang, Longtan shales), we conducted complementary analyses with field emission-scanning electron microscopy (FE-SEM), mercury intrusion capillary pressure (MICP), (CO 2 N ) sorption isotherm, contact angle, spontaneous imbibition, as well saturated diffusion tracer distribution mapped laser ablation-inductively coupled plasma-mass spectrometry. The use water n-decane fluids enables us examine hydrophilic hydrophobic networks shale, resultant imbibition slopes demonstrate that Longmaxi has high its high-development both well-connected organic inorganic pores. Limited distances associated tortuosity (from MICP analyses) are consistent predominant presence nano-sized throats (3–50 nm) isotherm tests. types, development degree, connection directly supported by FE-SEM-imaging. Overall, variable limited samples will affect hydrocarbon preservation recovery.

参考文章(61)
Hubert E. King, Aaron P. R. Eberle, Clifford C. Walters, Chris E. Kliewer, Deniz Ertas, Chuong Huynh, Pore Architecture and Connectivity in Gas Shale Energy & Fuels. ,vol. 29, pp. 1375- 1390 ,(2015) , 10.1021/EF502402E
C. Legens, T. Palermo, H. Toulhoat, A. Fafet, P. Koutsoukos, Carbonate rock wettability changes induced by organic compound adsorption Journal of Petroleum Science and Engineering. ,vol. 20, pp. 277- 282 ,(1998) , 10.1016/S0920-4105(98)00031-X
Ma Shouxiang, Norman R. Morrow, Xiaoyun Zhang, Generalized scaling of spontaneous imbibition data for strongly water-wet systems Journal of Petroleum Science and Engineering. ,vol. 18, pp. 165- 178 ,(1997) , 10.1016/S0920-4105(97)00020-X
C.R. Clarkson, N. Solano, R.M. Bustin, A.M.M. Bustin, G.R.L. Chalmers, L. He, Y.B. Melnichenko, A.P. Radliński, T.P. Blach, Pore structure characterization of North American shale gas reservoirs using USANS/SANS, gas adsorption, and mercury intrusion Fuel. ,vol. 103, pp. 606- 616 ,(2013) , 10.1016/J.FUEL.2012.06.119
Kewen Li, Scaling of spontaneous imbibition data with wettability included. Journal of Contaminant Hydrology. ,vol. 89, pp. 218- 230 ,(2007) , 10.1016/J.JCONHYD.2006.09.009
A. J. Katz, A. H. Thompson, Quantitative prediction of permeability in porous rock Physical Review B. ,vol. 34, pp. 8179- 8181 ,(1986) , 10.1103/PHYSREVB.34.8179
Taotao Cao, Zhiguang Song, Sibo Wang, Xinxing Cao, Yan Li, Jia Xia, Characterizing the pore structure in the Silurian and Permian shales of the Sichuan Basin, China Marine and Petroleum Geology. ,vol. 61, pp. 140- 150 ,(2015) , 10.1016/J.MARPETGEO.2014.12.007
Chaohua Guo, Jianchun Xu, Keliu Wu, Mingzhen Wei, Songyuan Liu, Study on Gas Flow through Nano Pores of Shale Gas Reservoirs Fuel. ,vol. 143, pp. 107- 117 ,(2015) , 10.1016/J.FUEL.2014.11.032