The structure of C60Ph5Cl and C60Ph5H, formed via electrophilic aromatic substitution
作者： Anthony G. Avent , Paul R. Birkett , Jonathan D. Crane , Adam D. Darwish , G. John Langley
DOI: 10.1039/C39940001463
关键词:
摘要: Reaction of C60Cl6 with benzene/FeCl3yields C60Ph5Cl which is readily reduced to C60Ph5H, the main product reacting C60 Br2/FeCl3/benzene; both compounds have been characterised by NMR spectroscopy.
rsc.org
sci-hub.se 参考文章(3)
C. C. Henderson, P. A. Cahill, C60H2: Synthesis of the Simplest C60 Hydrocarbon Derivative Science. ,vol. 259, pp. 1885- 1887 ,(1993) , 10.1126/SCIENCE.259.5103.1885
George A. Olah, Imre Bucsi, Christian Lambert, Robert Aniszfeld, Nirupam J. Trivedi, Dilip K. Sensharma, G. K. Surya Prakash, Chlorination and bromination of fullerenes. Nucleophilic methoxylation of polychlorofullerenes and their aluminum trichloride catalyzed Friedel-Crafts reaction with aromatics to polyarylfullerenes Journal of the American Chemical Society. ,vol. 113, pp. 9385- 9387 ,(1991) , 10.1021/JA00024A063
Fred N. Tebbe, James Y. Becker, D. Bruce Chase, Lawrence E. Firment, Edward R. Holler, Brian S. Malone, Paul J. Krusic, E. Wasserman, Multiple, reversible chlorination of C60 Journal of the American Chemical Society. ,vol. 113, pp. 9900- 9901 ,(1991) , 10.1021/JA00026A052