An n- to p-type conductivity transition induced by oxygen adsorption on α-Fe2O3

作者: A. Gurlo , N. Bârsan , A. Oprea , M. Sahm , T. Sahm

DOI: 10.1063/1.1794853

关键词:

摘要: The simultaneous measurements of conductance and work function changes induced by gaseous ambient have been performed on α-Fe2O3 thick film polycrystalline samples kept at 280 °C exposed to different atmospheres. switching from n- p-type conductivity is shown an electronic origin, which due the oxygen adsorption formation a surface inversion layer and, therefore, conduction type. modeling n–p described in terms dependence band bending ambient.

参考文章(16)
R.F.G. Gardner, F. Sweett, D.W. Tanner, The electrical properties of alpha ferric oxide—I. Journal of Physics and Chemistry of Solids. ,vol. 24, pp. 1175- 1181 ,(1963) , 10.1016/0022-3697(63)90234-8
A. BIELAŃSKI, J. DEREŃ, J. HABER, Electric Conductivity and Catalytic Activity of Semiconducting Oxide Catalysts Nature. ,vol. 179, pp. 668- 669 ,(1957) , 10.1038/179668A0
N. Bârsan, R. Grigorovici, R. Ionescu, Manuela Motronea, Ana Vancu, Mechanism of gas detection in polycrystalline thick film SnO2 sensors Thin Solid Films. ,vol. 171, pp. 53- 63 ,(1989) , 10.1016/0040-6090(89)90033-3
Nancy Savage, Brian Chwieroth, Arwa Ginwalla, Bruce R. Patton, Sheikh A. Akbar, Prabir K. Dutta, Composite n–p semiconducting titanium oxides as gas sensors Sensors and Actuators B-chemical. ,vol. 79, pp. 17- 27 ,(2001) , 10.1016/S0925-4005(01)00843-7
B.W Licznerski, K Nitsch, H Teterycz, K Wiśniewski, The influence of Rh surface doping on anomalous properties of thick-film SnO2 gas sensors☆ Sensors and Actuators B-chemical. ,vol. 79, pp. 157- 162 ,(2001) , 10.1016/S0925-4005(01)00862-0
G. Korotcenkov, V. Brinzari, V. Golovanov, A. Cerneavschi, V. Matolin, A. Tadd, Acceptor-like behavior of reducing gases on the surface of n-type In2O3 Applied Surface Science. ,vol. 227, pp. 122- 131 ,(2004) , 10.1016/J.APSUSC.2003.11.051
K. Galatsis, L. Cukrov, W. Wlodarski, P. McCormick, K. Kalantar-zadeh, E. Comini, G. Sberveglieri, p-and n-type Fe-doped SnO2 gas sensors fabricated by the mechanochemical processing technique Sensors and Actuators B-chemical. ,vol. 93, pp. 562- 565 ,(2003) , 10.1016/S0925-4005(03)00233-8
David E. Williams, Semiconducting oxides as gas-sensitive resistors Sensors and Actuators B-chemical. ,vol. 57, pp. 1- 16 ,(1999) , 10.1016/S0925-4005(99)00133-1