Cubane Ru4(CO)8 cluster containing 4 pyridine-methanol ligands as a highly efficient photoelectrocatalyst for oxygen evolution reaction from water
作者： Pradeep Mathur , Pradeep Mathur , Shaikh M. Mobin , Ajeet Singh , Neha Choudhary
DOI: 10.1016/J.JORGANCHEM.2021.121769
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摘要: Abstract The preparation of Ru4 ruthenium-cubane cluster [Ru4(hmp)4(CO)8] 1 containing four 2-pyCH2O-bridged ligands (hmp) is described along with its remarkable application in a photoelectrochemical cell (PEC) as an efficient anodic material for solar water splitting. catalyst assembly undergoes light-driven oxidation at pH 13.5 1M NaOH. With illumination using white light source 100 mW cm−2, photocurrents up to 0.44 mA cm−2 were observed under 0.95 V vs Ag/AgCl applied bias Faradaic efficiency O2 production 91.9 %. result establishes important candidate electrodes photocatalytic
sci-hub.st 参考文章(61)
Fusheng Li, Ke Fan, Lei Wang, Quentin Daniel, Lele Duan, Licheng Sun, Immobilizing Ru(bda) Catalyst on a Photoanode via Electrochemical Polymerization for Light-Driven Water Splitting ACS Catalysis. ,vol. 5, pp. 3786- 3790 ,(2015) , 10.1021/CS502115F
Serkan Esiner, Robin E. M. Willems, Alice Furlan, Weiwei Li, Martijn M. Wienk, René A. J. Janssen, Photoelectrochemical water splitting in an organic artificial leaf Journal of Materials Chemistry. ,vol. 3, pp. 23936- 23945 ,(2015) , 10.1039/C5TA07325A
George M. Sheldrick, Crystal structure refinement with SHELXL Acta Crystallographica Section C-crystal Structure Communications. ,vol. 71, pp. 3- 8 ,(2015) , 10.1107/S2053229614024218
David James Martin, Philip James Thomas Reardon, Savio J. A. Moniz, Junwang Tang, Visible Light-Driven Pure Water Splitting by a Nature-Inspired Organic Semiconductor-Based System Journal of the American Chemical Society. ,vol. 136, pp. 12568- 12571 ,(2014) , 10.1021/JA506386E
Meidan Ye, Jiaojiao Gong, Yuekun Lai, Changjian Lin, Zhiqun Lin, High-Efficiency Photoelectrocatalytic Hydrogen Generation Enabled by Palladium Quantum Dots-Sensitized TiO2 Nanotube Arrays Journal of the American Chemical Society. ,vol. 134, pp. 15720- 15723 ,(2012) , 10.1021/JA307449Z
N. S. Lewis, D. G. Nocera, Powering the planet: Chemical challenges in solar energy utilization Proceedings of the National Academy of Sciences of the United States of America. ,vol. 103, pp. 15729- 15735 ,(2006) , 10.1073/PNAS.0603395103
Takashi Hisatomi, Jun Kubota, Kazunari Domen, Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting Chemical Society Reviews. ,vol. 43, pp. 7520- 7535 ,(2014) , 10.1039/C3CS60378D
R. Mason, A. I. M. Rae, The crystal structure of ruthenium carbonyl, Ru3(CO)12 Journal of the Chemical Society A: Inorganic, Physical, Theoretical. pp. 778- 779 ,(1968) , 10.1039/J19680000778
Bobak Gholamkhass, Hiroaki Mametsuka, Kazuhide Koike, Toyoaki Tanabe, Masaoki Furue, Osamu Ishitani, Architecture of Supramolecular Metal Complexes for Photocatalytic CO2 Reduction: Ruthenium−Rhenium Bi- and Tetranuclear Complexes Inorganic Chemistry. ,vol. 44, pp. 2326- 2336 ,(2005) , 10.1021/IC048779R
Scott G. Mitchell, Carsten Streb, Haralampos N. Miras, Thomas Boyd, De-Liang Long, Leroy Cronin, Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture Nature Chemistry. ,vol. 2, pp. 308- 312 ,(2010) , 10.1038/NCHEM.581