Electrochemical Properties of Silicic Acid Sols
作者： J. N. MUKHERJEE , B. CHATTERJEE
DOI: 10.1038/155085A0
关键词:
摘要: THE properties of silicic acid sols have been studied by several investigators1–10. Differences opinion1,2,3 expressed as to whether the possess any intrinsic character. In a number publications from this laboratory interactions with bases11,12,13,14, neutral salts15,16 and acids17,18 discussed. The even after purification prolonged electro-dialysis free acidities order 10–4 N. Their ultra-filtrates practically reaction showing that mobile H+ ions associated continued buffer action beyond first inflexion point takes place, second (Fig. 2) between PH 11·0 11·7 corresponding formation NaHSiO3 is observed13. An at pH 11·8 in titration curves sol concentrated alkali has observed Tread-well Konig4.
nature.com
harvard.edu
sci-hub.se 参考文章(11)
Gunnar Hägg, Untersuchungen über Silicate. III. Die Hydrolyse der Natriumsilicate Zeitschrift für anorganische und allgemeine Chemie. ,vol. 155, pp. 21- 41 ,(1926) , 10.1002/ZAAC.19261550104
W. D. Treadwell, W. Wieland, Zur Kenntnis der Kieselsäurehydrate Helvetica Chimica Acta. ,vol. 13, pp. 842- 864 ,(1930) , 10.1002/HLCA.19300130512
Jnanendra Nath Mukherjee, Bivas Chandra Ghosh, K. Krishnamurti, Gajendra Narayan Ghosh, Subhendu Kumar Mitra, Bankim Chandra Roy, CCCCIII.—Interaction between hydrated silica and neutral electrolytes in its relation to the nature of hydrolytic adsorption J. Chem. Soc.. ,vol. 129, pp. 3023- 3033 ,(1926) , 10.1039/JR9262903023
Alfred Francis Joseph, John Stanley Hancock, CCXXII.—The action of silica on electrolytes J. Chem. Soc., Trans.. ,vol. 123, pp. 2022- 2025 ,(1923) , 10.1039/CT9232302022
J. N. MUKHERJEE, Adsorption of Acids by Purified Silica Nature. ,vol. 115, pp. 497- 497 ,(1925) , 10.1038/115497B0
Wolfgang Pauli, Emerich Valk�, Beiträge zur allgemeinen Kolloidchemie XVI. Die Konstitution der Kieselsäuresole I Colloid and Polymer Science. ,vol. 36, pp. 334- 340 ,(1925) , 10.1007/BF01451973
Alfred Francis Joseph, Henry Bowen Oakley, CCCLXXXVIII.—The action of silica on electrolytes. Part II J. Chem. Soc., Trans.. ,vol. 127, pp. 2813- 2818 ,(1925) , 10.1039/CT9252702813
W. D. Treadwell, W. König, Zur Kenntnis der kolloiden Kieselsäure II Helvetica Chimica Acta. ,vol. 16, pp. 468- 478 ,(1933) , 10.1002/HLCA.19330160163
Jnanendra Nath Mukherjee, XXIX. The adsorption of ions Philosophical Magazine Series 1. ,vol. 44, pp. 321- 346 ,(1922) , 10.1080/14786440808634003
R. W. Harman, Aqueous Solutions of Sodium Silicates. VII SILICATE IONS. ELECTROMETRIC TITRATIONS: DIFFUSION: COLORIMETRIC ESTIMATION. The Journal of Physical Chemistry. ,vol. 31, pp. 616- 625 ,(1927) , 10.1021/J150274A015