Preparation and properties of laser dye-ORMOSIL composites

作者: Hsin-Tah Lin , E. Bescher , J. D. Mackenzie , Hongxing Dai , O. M. Stafsudd

DOI: 10.1007/BF00541615

关键词:

摘要: Various organic laser dyes have been incorporated into organically modified silicates (ORMOSILs), derived from polydimethylsiloxane and tetraethoxysilane. These sol-gel PT-ORMOSILs proved to be good hosts for the in terms of stability optical gain. Some dyes, example, Rhodamine 610, 620, 640, shown higher than methyl alcohol. The Rh6G a PT-ORMOSIL is 76% dry nitrogen air, because contribution oxygen and/or moisture dye degradation processes. fluorescence intensity Rh610 was enhanced by factor 3.9 as temperature cooled room 77 K.

参考文章(15)
C. Jeffrey Brinker, George W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing ,(1990)
Akio Makishima, Toshiro Tani, Preparation of Amorphous Silicas Doped with Organic Molecules by the Sol‐Gel Process Journal of the American Ceramic Society. ,vol. 69, ,(1986) , 10.1111/J.1151-2916.1986.TB04755.X
Toshiro Tani, Hiroshi Namikawa, Kazuo Arai, Akio Makishima, Photochemical hole‐burning study of 1,4‐dihydroxyanthraquinone doped in amorphous silica prepared by alcoholate method Journal of Applied Physics. ,vol. 58, pp. 3559- 3565 ,(1985) , 10.1063/1.335731
D. A. Gromov, K. M. Dyumaev, A. A. Manenkov, A. P. Maslyukov, G. A. Matyushin, V. S. Nechitailo, A. M. Prokhorov, Efficient plastic-host dye lasers Journal of The Optical Society of America B-optical Physics. ,vol. 2, pp. 1028- 1031 ,(1985) , 10.1364/JOSAB.2.001028
John McKiernan, Jean Claude Pouxviel, Bruce Dunn, Jeffrey I. Zink, Rigidochromism as a probe of gelation and densification of silicon and mixed aluminum-silicon alkoxides The Journal of Physical Chemistry. ,vol. 93, pp. 2129- 2133 ,(1989) , 10.1021/J100342A081
J. C. Pouxviel, B. Dunn, J. I. Zink, Fluorescence study of aluminosilicate sols and gels doped with hydroxy trisulfonated pyrene The Journal of Physical Chemistry. ,vol. 93, pp. 2134- 2139 ,(1989) , 10.1021/J100342A082
David Avnir, David Levy, Renata Reisfeld, The nature of the silica cage as reflected by spectral changes and enhanced photostability of trapped Rhodamine 6G The Journal of Physical Chemistry. ,vol. 88, pp. 5956- 5959 ,(1984) , 10.1021/J150668A042
D.I. Santos, M.A. Aegerter, C.H. Brito Cruz, M. Scarparo, J. Zarzycki, Optical properties of dye molecules adsorbed on fractal structures Journal of Non-crystalline Solids. ,vol. 82, pp. 165- 170 ,(1986) , 10.1016/0022-3093(86)90126-2
Renata Reisfeld, Rivka Zusman, Yoram Cohen, Marek Eyal, The spectroscopic behaviour of rhodamine 6G in polar and non-polar solvents and in thin glass and PMMA films Chemical Physics Letters. ,vol. 147, pp. 142- 147 ,(1988) , 10.1016/0009-2614(88)85073-5
Edward T. Knobbe, Bruce Dunn, Peter D. Fuqua, Fumito Nishida, Laser behavior and photostability characteristics of organic dye doped silicate gel materials. Applied Optics. ,vol. 29, pp. 2729- 2733 ,(1990) , 10.1364/AO.29.002729