The effect of inhomogeneous broadening on optical strong field spectroscopy
作者： M. Morillo , R. I. Cukier
DOI: 10.1063/1.481995
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摘要: We show that a recent theory of strong field spectroscopy (SFS) [R. I. Cukier and M. Morillo, Phys. Rev. B 57, 6972 (1998), Morillo R. Cukier, J. Chem. 110, 7966 (1999)] can be used to circumvent the effects inhomogeneous broadening on this spectroscopy. In SFS, external is connect, with transition dipole, two electronic states solute immersed in medium. The dephasing due medium characterized via power absorbed by solute. average P(t) for resonant, fields exhibits an oscillatory decay time, reflecting finite change population difference arising from coupling rate d≡Δ2τc, where Δ τc are, respectively, strength time constant correlation function characterizing solute–medium coupling. very rapid, 10–100 fs scale, necessitates indirect p...
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sci-hub.se 参考文章(27)
Shaul Mukamel, Principles of Nonlinear Optical Spectroscopy ,(1995)
R. I. Cukier, Jianjun Zhu, SIMULATION OF EXCITED STATE PROTON TRANSFER REACTION KINETICS Journal of Chemical Physics. ,vol. 110, pp. 9587- 9597 ,(1999) , 10.1063/1.478924
Kenneth W. DeLong, Bern Kohler, Kent Wilson, David N. Fittinghoff, Rick Trebino, Pulse retrieval in frequency-resolved optical gating based on the method of generalized projections. Optics Letters. ,vol. 19, pp. 2152- 2154 ,(1994) , 10.1364/OL.19.002152
Wim P. de Boeij, Maxim S. Pshenichnikov, Douwe A. Wiersma, MODE SUPPRESSION IN THE NON-MARKOVIAN LIMIT BY TIME-GATED STIMULATED PHOTON ECHO Journal of Chemical Physics. ,vol. 105, pp. 2953- 2960 ,(1996) , 10.1063/1.472812
Andrius Baltuška, Maxim S. Pshenichnikov, Douwe A. Wiersma, Amplitude and phase characterization of 4.5-fs pulses by frequency-resolved optical gating Optics Letters. ,vol. 23, pp. 1474- 1476 ,(1998) , 10.1364/OL.23.001474
Peijun Cong, Yi Jing Yan, Hans P. Deuel, John D. Simon, Non‐Markovian optical dephasing dynamics in room temperature liquids investigated by femtosecond transient absorption spectroscopy: Theory and experiment Journal of Chemical Physics. ,vol. 100, pp. 7855- 7866 ,(1994) , 10.1063/1.466832
R. I. Cukier, M. Morillo, External-field effects on molecular electronic transitions in charge-transfer systems Physical Review B. ,vol. 57, pp. 6972- 6977 ,(1998) , 10.1103/PHYSREVB.57.6972
Minhaeng Cho, Jae-Young Yu, Taiha Joo, Yutaka Nagasawa, Sean A. Passino, Graham R. Fleming, The Integrated Photon Echo and Solvation Dynamics The Journal of Physical Chemistry. ,vol. 100, pp. 11944- 11953 ,(1996) , 10.1021/JP9601983
Daniel Thorn Leeson, Otto Berg, Douwe A. Wiersma, Low-Temperature Protein Dynamics Studied by the Long-Lived Stimulated Photon Echo The Journal of Physical Chemistry. ,vol. 98, pp. 3913- 3916 ,(1994) , 10.1021/J100065A056
Taiha Joo, Yiwei Jia, Jae‐Young Yu, Matthew J. Lang, Graham R. Fleming, Third-order nonlinear time domain probes of solvation dynamics Journal of Chemical Physics. ,vol. 104, pp. 6089- 6108 ,(1996) , 10.1063/1.471276