Nanoparticle-loaded highly flexible fibrous structures exhibiting desirable thermoelectric properties

作者: Anis Mohammadi , Afsaneh Valipouri , Saeed Salimian

DOI: 10.1016/J.DIAMOND.2018.04.018

关键词:

摘要: Abstract Thermoelectric, the science of transforming heat to electrical energy or vice versa, provides possibility reserve losses as an energy, which is called green energy. In recent years, producing a wearing thermoelectric generator that capable using human body temperature receives great interest. this research, nanocomposite Polyvinylpyrrolidone (PVP)/carbon nanotubes (CNTs)/copper oxide (CuO) nanoparticles were used in order produce current from losses. The structures prepared two methods electrospinning and coating fabrics with homogenous solution PVP, CNTs CuO nanoparticles. SEM, XRD, TEM FTIR analysis study structural morphological characteristics nanocomposite. results showed fabric coated mixture 20:20 (wt%) CNT nano-particles had Seebeck coefficient 39.21 μV/K conductivity 3.5 × 10−2 S/cm best properties. Moreover, indicated nanofibers fabricated via consisted (CuO: CNT) up 29.13 μV/K 2.114 × 10−4 S/cm.

参考文章(38)
David Michael Rowe, CRC Handbook of Thermoelectrics CRC Press. ,(1995) , 10.1201/9781420049718
Corey A. Hewitt, Alan B. Kaiser, Siegmar Roth, Matt Craps, Richard Czerw, David L. Carroll, Multilayered carbon nanotube/polymer composite based thermoelectric fabrics. Nano Letters. ,vol. 12, pp. 1307- 1310 ,(2012) , 10.1021/NL203806Q
Wael Salalha, Yael Dror, Rafail L. Khalfin, Yachin Cohen, Alexander L. Yarin, Eyal Zussman, Single-walled carbon nanotubes embedded in oriented polymeric nanofibers by electrospinning. Langmuir. ,vol. 20, pp. 9852- 9855 ,(2004) , 10.1021/LA048536B
Qingbiao Yang, Zhenyu Li, Youliang Hong, Yiyang Zhao, Shilun Qiu, Ce Wang, Yen Wei, Influence of solvents on the formation of ultrathin uniform poly(vinyl pyrrolidone) nanofibers with electrospinning Journal of Polymer Science Part B. ,vol. 42, pp. 3721- 3726 ,(2004) , 10.1002/POLB.20222
F. Yakuphanoglu, B. F. Şenkal, Electronic and Thermoelectric Properties of Polyaniline Organic Semiconductor and Electrical Characterization of Al/PANI MIS Diode Journal of Physical Chemistry C. ,vol. 111, pp. 1840- 1846 ,(2007) , 10.1021/JP0653050
N. T. Kemp, A. B. Kaiser, H. J. Trodahl, B. Chapman, R. G. Buckley, A. C. Partridge, P. J. S. Foot, Effect of ammonia on the temperature-dependent conductivity and thermopower of polypyrrole Journal of Polymer Science Part B. ,vol. 44, pp. 1331- 1338 ,(2006) , 10.1002/POLB.20792
Nayereh Soltani, Elias Saion, Maryam Erfani, Khadijeh Rezaee, Ghazaleh Bahmanrokh, Gregor PC Drummen, Afarin Bahrami, Mohd Zobir Hussein, None, Influence of the Polyvinyl Pyrrolidone Concentration on Particle Size and Dispersion of ZnS Nanoparticles Synthesized by Microwave Irradiation International Journal of Molecular Sciences. ,vol. 13, pp. 12412- 12427 ,(2012) , 10.3390/IJMS131012412
Xue-feng Qian, Jie Yin, Shuang Feng, Shu-hong Liu, Zi-kang Zhu, Preparation and characterization of polyvinylpyrrolidone films containing silver sulfide nanoparticles Journal of Materials Chemistry. ,vol. 11, pp. 2504- 2506 ,(2001) , 10.1039/B103708K
Virgil Andrei, Kevin Bethke, Klaus Rademann, Copper(I) oxide based thermoelectric powders and pastes with high Seebeck coefficients Applied Physics Letters. ,vol. 105, pp. 233902- ,(2014) , 10.1063/1.4903832
Jihui Yang, Thierry Caillat, Thermoelectric Materials for Space and Automotive Power Generation Mrs Bulletin. ,vol. 31, pp. 224- 229 ,(2006) , 10.1557/MRS2006.49